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Merck
CN

201073

Sigma-Aldrich

三仲丁氧基铝

97%

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别名:
仲丁醇铝
线性分子式:
Al[OCH(CH3)C2H5]3
CAS号:
分子量:
246.32
Beilstein:
3910908
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

97%

形式

liquid

自燃温度

763 °F

expl. lim.

9.8 %

反应适用性

core: aluminum

bp

200-206 °C/30 mmHg (lit.)

密度

0.967 g/mL at 25 °C (lit.)

SMILES字符串

CCC(C)O[Al](OC(C)CC)OC(C)CC

InChI

1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3

InChI key

WOZZOSDBXABUFO-UHFFFAOYSA-N

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一般描述

Aluminum-tri-sec-butoxide is a metal organic chemical vapor deposition precursor and a chelating agent. It is widely used as a sol-gel precursor to deposit alumina thin films by atomic layer deposition method.

应用

Aluminum-tri-sec-butoxide can be used as a precursor :
  • To prepare Al2O3-based quasi-solid electrolyte for Li metal anodes. This ensures long cycle lifetime and high constant current density.
  • To synthesize nanospinel MgAl2O4 powder by a sol–gel method at low-temperature processing.
  • To fabricate transparent superhydrophobic aluminum oxide thin films to prevent soiling of solar panels.
  • To synthesize mesoporous alumina with large surface area to fabricate a functional interlayer for separator coating in a Li–S battery. It helps to suppress the shuttle effect and enhances cyclic stability andrateperformance.

特点和优势

  • Suitable for thin film deposition
  • Solubility in various solvents allows for the facile preparation of solution-based precursors
  • High thermal stability
  • Facilitates the anchoring of catalytic metal nanoparticles onto substrates

已用于制备高表面积氧化铝,其中以 2,4-戊二酮(Aldrich 产品 P775-4)作为螯合剂。

象形图

FlameSkull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Chem. Abstr., 124, 328279f-328279f (1996)
Clark, H.W. et al.
Microporous Mater., 6, 115-115 (1996)
Vaudry, F. et al.
Chemistry of Materials, 8, 1451-1451 (1996)
Polykarpos A Lazaridis et al.
Frontiers in chemistry, 6, 295-295 (2018-08-04)
The valorization of lignin that derives as by product in various biomass conversion processes has become a major research and technological objective. The potential of the production of valuable mono-aromatics (BTX and others) and (alkyl)phenols by catalytic fast pyrolysis of
Federico Veronesi et al.
Materials (Basel, Switzerland), 12(5) (2019-03-15)
The search for surfaces with non-wetting behavior towards water and low-surface tension liquids affects a wide range of industries. Surface wetting is regulated by morphological and chemical features interacting with liquid phases under different ambient conditions. Most of the approaches

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