197335
硼酸三异丙酯
≥98%
别名:
三异丙基硼酸酯, 三异丙氧基硼烷, 异丙醇硼
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关于此项目
线性分子式:
[(CH3)2CHO]3B
化学文摘社编号:
分子量:
188.07
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-529-9
Beilstein/REAXYS Number:
1701469
MDL number:
产品名称
硼酸三异丙酯, ≥98%
form
liquid
InChI key
NHDIQVFFNDKAQU-UHFFFAOYSA-N
InChI
1S/C9H21BO3/c1-7(2)11-10(12-8(3)4)13-9(5)6/h7-9H,1-6H3
SMILES string
CC(C)OB(OC(C)C)OC(C)C
vapor pressure
76 mmHg ( 75 °C)
assay
≥98%
impurities
1% isopropanol
refractive index
n20/D 1.376 (lit.)
bp
139-141 °C (lit.)
density
0.815 g/mL at 25 °C (lit.)
Quality Level
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Application
用于 1-取代萘的邻位硼化，继而与芳基卤化物进行钯催化偶联。
General description
具有良好热性能的三烷基硼酸酯。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
62.6 °F - closed cup
flash_point_c
17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis, 3478-3478 (2006)
Tetrahedron, 60, 4887-4893 (2004)
Yersica Rios Yepes et al.
Dalton transactions (Cambridge, England : 2003), 49(4), 1124-1134 (2020-01-03)
A set of alkyl aluminum complexes supported by non-symmetric ferrocenyl amidine ligands were used as catalysts for the preparation of cyclic carbonates from epoxides and carbon dioxide using Bu4NI as a co-catalyst. A modified method for the synthesis of aminoferrocene
Flexible interlocked porous frameworks allow quantitative photoisomerization in a crystalline solid.
Yongtai Zheng et al.
Nature communications, 8(1), 100-100 (2017-07-26)
Photochromic molecules have shown much promise as molecular components of stimuli-responsive materials, but despite recent achievements in various photoresponsive materials, quantitative conversion in photochemical reactions in solids is hampered by the lack of intrinsic structural flexibility available to release stress
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