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Merck
CN

196819

Sigma-Aldrich

四氟邻苯二腈

95%

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别名:
3,4,5,6-四氟邻苯二甲腈, 3,4,5,6-四氟邻苯二腈
线性分子式:
C6F4(CN)2
CAS号:
分子量:
200.09
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

mp

81-86 °C (lit.)

SMILES字符串

Fc1c(F)c(F)c(C#N)c(C#N)c1F

InChI

1S/C8F4N2/c9-5-3(1-13)4(2-14)6(10)8(12)7(5)11

InChI key

OFLRJMBSWDXSPG-UHFFFAOYSA-N

一般描述

四氟邻苯二甲腈可与以下物质反应:
  • 铜、氯化铜(I)或氯化铜(II)生成十六氟铜酞菁铜(II)
  • 2-羟基六氟-2-丙基苯的钾盐生成2-苯基-2-(3,4-二氰基-三氟苯氧基)六氟丙烷
  • 1,3-(2-羟基六氟-2-丙基)苯的二钾盐生成氟化邻苯二甲腈树脂

应用

四氟邻苯二甲腈已被用于合成二氯亚酞菁二聚体

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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The synthesis of highly fluorinated phthalonitrile resins and cure studies.
Keller TM and Griffith JR.
Journal of Fluorine Chemistry, 13(4), 315-324 (1979)
Polyfluoroarenes. Part XI. Reactions of tetrafluorophthalonitrile with nucleophilic reagents.
Birchall JM, et al.
J. Chem. Soc. Sect. C, 3, 456-462 (1970)
Synthesis, separation, and characterization of the topoisomers of fused bicyclic subphthalocyanine dimers.
Christian G Claessens et al.
Angewandte Chemie (International ed. in English), 41(14), 2561-2565 (2002-08-31)
Thi Hai Quyen Nguyen et al.
Physical chemistry chemical physics : PCCP, 22(15), 7699-7709 (2020-03-07)
The transport of both electrons and ions in organic mixed ionic and electronic conductors such as phthalocyanines, is essential to allow redox reactions of entire films and, hence, to impart electrochromism. Thin films of a new type, tetrakis-perfluoroisopropyl-perfluoro phthalocyanine, F40PcCu
Dongkun Yu et al.
The journal of physical chemistry. B, 123(23), 4958-4966 (2019-05-24)
The concept of eutectic molecular liquids (EMLs) was defined, and a strategy to form EMLs based on noncovalent interactions was proposed. We verified the formation and investigated the properties, interaction sites, and interaction energies of the obtained 16 EMLs. Moreover

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