196657
1-氟萘
99%
别名:
α-氟萘
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关于此项目
经验公式（希尔记法）:
C10H7F
化学文摘社编号:
分子量:
146.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-287-0
Beilstein/REAXYS Number:
1906413
MDL number:
产品名称
1-氟萘, 99%
InChI key
CWLKTJOTWITYSI-UHFFFAOYSA-N
InChI
1S/C10H7F/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
SMILES string
Fc1cccc2ccccc12
assay
99%
form
liquid
refractive index
n20/D 1.593 (lit.)
bp
215 °C (lit.)
mp
−13 °C (lit.)
density
1.1322 g/mL at 20 °C (lit.)
functional group
fluoro
Quality Level
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Application
1-氟萘用于 t -BuLi 介导的 6-取代菲啶的合成 。它也被用于合成 LY248686，一种 5-羟色胺和去甲肾上腺素摄取的强效抑制剂 。
General description
研究了 O 2 和 1-氟萘混合物在气相中的闪光光解反应 。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Asymmetric synthesis and absolute stereochemistry of LY248686.
Deeter J, et al.
Tetrahedron Letters, 31(49), 7101-7104 (1990)
Jan Pawlas et al.
Organic letters, 4(16), 2687-2690 (2002-08-03)
[reaction: see text] A one-pot, t-BuLi-induced synthesis of 6-substituted phenanthridines from fluoroarenes and nitriles via 1,2-arynes is reported. Aryl- and hetaryl nitriles, cyanamides, and trimethylacetonitrile gave phenanthridine products. The method was extended to provide bisphenanthridine 10 by a one-pot bis-cyclization
Formation of O 2 (1Sigma g+) by 1-fluoronaphthalene sensitization.
Andrews LJ and Abrahamson EW.
Chemical Physics Letters, 10, 113-116 (1971)
C E Cerniglia et al.
Applied and environmental microbiology, 48(2), 294-300 (1984-08-01)
The metabolism of 1-fluoronaphthalene by Cunninghamella elegans ATCC 36112 was studied. The metabolites were isolated by reverse-phase high-pressure liquid chromatography and characterized by the application of UV absorption, 1H nuclear magnetic resonance, and mass spectral techniques. C. elegans oxidized 1-fluoronaphthalene
Peter Wipf et al.
Organic letters, 5(7), 1155-1158 (2003-03-28)
[reaction: see text] Electron-rich dinaphthyl ethers were synthesized by S(N)Ar reactions between naphthols and activated fluoronaphthalenes. 2-tert-Butyl-1,1,3,3-tetramethylguanidine (Barton's base) was found to be an excellent, mild alternative to traditional inorganic bases for promoting the coupling reaction.
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