186252
己二酸二甲酯
≥99%
别名:
己二酸1,6-二甲酯, 己二酸二甲酯
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线性分子式:
CH3OCO(CH2)4COOCH3
化学文摘社编号:
分子量:
174.19
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
211-020-6
Beilstein/REAXYS Number:
1707443
MDL number:
产品名称
己二酸二甲酯, ≥99%
assay
≥99%
form
liquid
InChI key
UDSFAEKRVUSQDD-UHFFFAOYSA-N
InChI
1S/C8H14O4/c1-11-7(9)5-3-4-6-8(10)12-2/h3-6H2,1-2H3
SMILES string
COC(=O)CCCCC(=O)OC
vapor pressure
0.06 mmHg ( 20 °C)
autoignition temp.
680 °F
expl. lim.
8.1 %
refractive index
n20/D 1.428 (lit.)
bp
109-110 °C/14 mmHg (lit.)
mp
8 °C (lit.)
density
1.062 g/mL at 20 °C (lit.)
Quality Level
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Application
- 用于冷热能储存的微/纳米封装：己二酸二甲酯已封装在聚合物外壳中，用于改善热性能，使其适用于冷热能储存应用（Trivedi & Parameshwaran, 2022）。
- 通过非血红素铁(III)催化实现可持续生产：一种使用非血红素铁(III)催化剂通过氧化裂解儿茶酚生产己二酸二甲酯的方法强调了一种环保方法（Jastrzebski et al., 2015）。
- 用于己二腈生产的强化硝化：开发双金属氧化物催化剂，将己二酸二甲酯硝化为己二腈的过程显示出增强的活性和选择性，对于工业应用具有重要意义（Guo et al., 2023）。
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves
S A Simpson et al.
Archives of toxicology, 79(4), 224-230 (2005-02-04)
We have previously developed a rat nasal explant system for investigating upper respiratory tract toxicity, and the aims of this study were to determine whether heat shock protein (HSP) 70 is induced in this model following exposure to carbon tetrachloride
A microscopic and ultrastructural evaluation of dibasic esters (DBE) toxicity in rat nasal explants.
B A Trela et al.
Experimental and molecular pathology, 56(3), 208-218 (1992-06-01)
Dibasic esters (DBE) solvent has been demonstrated to induce a mild degeneration of the olfactory, but not the respiratory epithelium of the rat nasal cavity following a 90-day inhalation exposure. Previous work has demonstrated that acid phosphatase release is a
M A Medinsky et al.
Toxicology, 160(1-3), 165-172 (2001-03-14)
Inhalation is a common route by which individuals are exposed to toxicants. The air contains a multitude of gases and vapors that are brought into the respiratory tract with each breath. Depending upon the physical and chemical characteristics of the
Naz Chaibakhsh et al.
Biotechnology journal, 5(8), 848-855 (2010-07-16)
Dimethyl adipate (DMA) was synthesized by immobilized Candida antarctica lipase B-catalyzed esterification of adipic acid and methanol. To optimize the reaction conditions of ester production, response surface methodology was applied, and the effects of four factors namely, time, temperature, enzyme
Mar Serrano-Arnaldos et al.
Journal of biotechnology, 325, 91-99 (2020-11-15)
Esters from branched alcohols and dicarboxylic linear acids are widely used as lube bases due to their good performance at low temperatures. This work proposes a new process to synthesize bis(2-ethylbutyl) adipate and bis(2-ethylbutyl) sebacate by using the lipase-based catalyst
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