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Merck
CN

186252

Sigma-Aldrich

己二酸二甲酯

≥99%

别名:

己二酸1,6-二甲酯, 己二酸二甲酯

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About This Item

线性分子式:
CH3OCO(CH2)4COOCH3
CAS号:
分子量:
174.19
Beilstein:
1707443
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

蒸汽压

0.06 mmHg ( 20 °C)

质量水平

方案

≥99%

表单

liquid

自燃温度

680 °F

expl. lim.

8.1 %

折射率

n20/D 1.428 (lit.)

沸点

109-110 °C/14 mmHg (lit.)

mp

8 °C (lit.)

密度

1.062 g/mL at 20 °C (lit.)

SMILES字符串

COC(=O)CCCCC(=O)OC

InChI

1S/C8H14O4/c1-11-7(9)5-3-4-6-8(10)12-2/h3-6H2,1-2H3

InChI key

UDSFAEKRVUSQDD-UHFFFAOYSA-N

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应用

  • 用于冷热能储存的微/纳米封装:己二酸二甲酯已封装在聚合物外壳中,用于改善热性能,使其适用于冷热能储存应用(Trivedi & Parameshwaran, 2022)。
  • 通过非血红素铁(III)催化实现可持续生产:一种使用非血红素铁(III)催化剂通过氧化裂解儿茶酚生产己二酸二甲酯的方法强调了一种环保方法(Jastrzebski et al., 2015)。
  • 用于己二腈生产的强化硝化:开发双金属氧化物催化剂,将己二酸二甲酯硝化为己二腈的过程显示出增强的活性和选择性,对于工业应用具有重要意义(Guo et al., 2023)。

储存分类代码

10 - Combustible liquids

WGK

WGK 1

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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M A Medinsky et al.
Toxicology, 160(1-3), 165-172 (2001-03-14)
Inhalation is a common route by which individuals are exposed to toxicants. The air contains a multitude of gases and vapors that are brought into the respiratory tract with each breath. Depending upon the physical and chemical characteristics of the
B A Trela et al.
Experimental and molecular pathology, 56(3), 208-218 (1992-06-01)
Dibasic esters (DBE) solvent has been demonstrated to induce a mild degeneration of the olfactory, but not the respiratory epithelium of the rat nasal cavity following a 90-day inhalation exposure. Previous work has demonstrated that acid phosphatase release is a
S A Simpson et al.
Archives of toxicology, 79(4), 224-230 (2005-02-04)
We have previously developed a rat nasal explant system for investigating upper respiratory tract toxicity, and the aims of this study were to determine whether heat shock protein (HSP) 70 is induced in this model following exposure to carbon tetrachloride
Mar Serrano-Arnaldos et al.
Journal of biotechnology, 325, 91-99 (2020-11-15)
Esters from branched alcohols and dicarboxylic linear acids are widely used as lube bases due to their good performance at low temperatures. This work proposes a new process to synthesize bis(2-ethylbutyl) adipate and bis(2-ethylbutyl) sebacate by using the lipase-based catalyst
M S Bogdanffy et al.
Drug metabolism and disposition: the biological fate of chemicals, 19(1), 124-129 (1991-01-01)
Inhalation exposure of rats to dibasic esters revealed lesions of the nasal olfactory epithelium similar to those observed with other ester solvents. Female rats are more sensitive to these effects than are male rats. It has been proposed that carboxylesterase

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