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Merck
CN

183962

2,3-二氢苯并呋喃

99%

别名:

氯杀鼠灵

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关于此项目

经验公式(希尔记法):
C8H8O
化学文摘社编号:
分子量:
120.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-817-3
Beilstein/REAXYS Number:
111928
MDL number:
Assay:
99%
Form:
liquid
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refractive index

n20/D 1.549 (lit.)

bp

188-189 °C (lit.)

solubility

alcohol: soluble, carbon disulfide: soluble, chloroform: soluble, diethyl ether: soluble

density

1.065 g/mL at 25 °C (lit.)

InChI key

HBEDSQVIWPRPAY-UHFFFAOYSA-N

InChI

1S/C8H8O/c1-2-4-8-7(3-1)5-6-9-8/h1-4H,5-6H2

SMILES string

C1Cc2ccccc2O1

assay

99%

form

liquid

Quality Level

Gene Information

human ... CYP1A2(1544)

General description

已经研究了使用恶臭假单胞菌 UV4 的完整细胞生物转化 2,3-二氢苯并呋喃。2,3-二氢苯并呋喃是在苯并呋喃的催化加氢脱氧过程中形成的中间体

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

152.6 °F - closed cup

flash_point_c

67 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Xiangtai Meng et al.
Organic letters, 11(1), 137-140 (2008-12-05)
A new bifunctional phosphine catalyst, (2'-hydroxy-biphenyl-2-yl)-diethylphosphane (LBBA-1), was developed for the highly stereoselective synthesis of cis-2,3-dihydrobenzofurans via an aza-Morita-Baylis-Hillman/umpolung addition domino reaction of salicyl N-thiophosphinyl imines with electron-deficient allenes. Dual activation of both nucleophile and electrophile by the bifunctional catalyst
Guo-Hua Chu et al.
Bioorganic & medicinal chemistry letters, 15(23), 5114-5119 (2005-10-06)
Two novel chemical classes of kappa opioid receptor agonists, chroman-2-carboxamide derivatives and 2,3-dihydrobenzofuran-2-carboxamide derivatives, were synthesized. These agents exhibited high and selective affinity for the kappa opioid receptor.
Catalytic hydrodeoxygenation of benzofuran and o-ethylphenol.
Lee C-L and Ollis DF.
J. Catal., 87(2), 325-331 (1984)
Structures and stereochemical assignments of some novel chiral synthons derived from the biotransformation of 2, 3-dihydrobenzofuran and benzofuran by Pseudomonas putida.
Boyd DR, et al.
Tetrahedron Asymmetry, 4(6), 1307-1324 (1993)
Łukasz Albrecht et al.
Angewandte Chemie (International ed. in English), 50(52), 12496-12500 (2011-11-09)
Fine-tuning: Three types of optically active trans-2,3-disubstituted-2,3-dihydrobenzofurans having three contiguous stereogenic centers can be efficiently accessed by one-pot reaction cascades (see scheme; TMS = trimethylsilyl). High substitution diversity of the final products can be achieved from the same common precursors

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