175552
三氯硅烷
99%
别名:
三氯化硅, 三氯氢硅, 三氯硅烷, 硅氯仿
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关于此项目
线性分子式:
SiHCl3
化学文摘社编号:
分子量:
135.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
233-042-5
MDL number:
产品名称
三氯硅烷, 99%
InChI key
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
InChI
1S/Cl3HSi/c1-4(2)3/h4H
SMILES string
Cl[SiH](Cl)Cl
vapor density
1 (vs air)
vapor pressure
9.75 psi ( 20 °C)
assay
99%
form
liquid
expl. lim.
70 %
bp
32-34 °C (lit.)
density
1.342 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
以三氯氢硅为原料，通过还原 11-二环己基膦酰-12-苯基-9,10-二氢-9,10-乙烯蒽，合成了 11-二环己基膦-12-苯基-9,10-二氢-9,10-乙烯蒽。
其他可能的应用：
L -缬氨酸衍生物催化剂存在下 N -芳基酮亚胺的不对称还原形成仲胺。
衍生物活化的三氯硅烷是亚胺还原生成
对映体富集胺的有效试剂。
其他可能的应用：
- 在新型
L -缬氨酸衍生物催化剂存在下 N -芳基酮亚胺的不对称还原形成仲胺。
- 在 2,2′ 存在下咪唑啉酮硅氢化形成手性咪唑烷酮类化合物-双吡咯烷基路易斯碱有机催化剂。
- 手性 N -甲酰脯氨酸
衍生物活化的三氯硅烷是亚胺还原生成
对映体富集胺的有效试剂。
- 三氯氢硅与二甲基甲酰胺反应生成高价氢硅酸盐，后者可将醛还原为醇类，亚胺还原为胺类，也可用于醛的还原胺化。
General description
三氯硅烷可用作某些化学反应的还原剂，或作为起始材料合成各种有机硅化合物。三氯硅烷通常用于烯烃在钯催化剂存在下与手性单齿磷配体配位的不对称硅氢加成反应，生成手性有机硅烷。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
<-2.2 °F - Equilibrium method
flash_point_c
< -19 °C - Equilibrium method
ppe
Faceshields, Gloves, Goggles
法规信息
监管及禁止进口产品
此项目有
Yaosi Fang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 7(13), 2000310-2000310 (2020-07-17)
As an analogue to the vapor-liquid-solid process, the solution-liquid-solid (SLS) method offers a mild solution-phase route to colloidal 1D nanostructures with controlled sizes, compositions, and properties. However, direct growth of 1D nanostructure arrays through SLS processes remains in its infancy.
New organic activators for the enantioselective reduction of aromatic imines with trichlorosilane
Onomura O
Tetrahedron Letters, 47(22), 3751-3754 (2006)
Christophe Blaszykowski et al.
Langmuir : the ACS journal of surfaces and colloids, 28(5), 2318-2322 (2012-01-25)
We report herein three unprecedented alkyltrichlorosilane surface modifiers bearing pentafluorophenyl ester (PFP), benzothiosulfonate (BTS), or novel β-propiolactone (BPL) functionalizable terminal groups. Evidence is provided that these molecules can be prepared in very high purity (as assessed by NMR) through a
Wei Ouyang et al.
Proceedings of the National Academy of Sciences of the United States of America, 116(33), 16240-16249 (2019-07-31)
Rapid and reliable detection of ultralow-abundance nucleic acids and proteins in complex biological media may greatly advance clinical diagnostics and biotechnology development. Currently, nucleic acid tests rely on enzymatic processes for target amplification (e.g., PCR), which have many inherent issues
Palladium-catalyzed asymmetric hydrosilylation of styrenes with trichlorosilane
Han JW
Tetrahedron Asymmetry, 25(6-7), 479-484 (2014)
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