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About This Item
线性分子式:
CH3B(OH)2
CAS号:
分子量:
59.86
Beilstein:
1731087
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
97%
形式
solid
mp
91-94 °C (lit.)
SMILES字符串
CB(O)O
InChI
1S/CH5BO2/c1-2(3)4/h3-4H,1H3
InChI key
KTMKRRPZPWUYKK-UHFFFAOYSA-N
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应用
甲基硼酸可用作以下反应中的试剂：
- 钯催化的 Stille 和 Suzuki-Miyaura 交叉偶联。
- 微波加热的非均相钯（Pd）催化反应。
- 钌（Ru）催化甲硅烷基化反应
- 制备双（氨基丙酮）钛（Ti）催化剂，用于乙烯聚合反应。
- 使用氨基硫代氨基甲酸酯催化剂催化选择性不对称溴氨基环化和溴氨基环化。
- 制备药品和农用化学品的基础成分。
- 通过 Suzuki-Miyaura 偶联反应制备白杨类似物。
- 制备酪蛋白激酶 I 抑制剂。
- 在药物研发中，制备由磺胺药物药效团引导的不同 C-H 官能化。
- 通过铜催化与硼酸偶联，从二硫化物合成不对称一硫化物。
- 钯催化与烯醇酯偶联。
- 衍生用于GLC分析的多种碳水化合物和生物活性化合物。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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