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Merck
CN

163813

Sigma-Aldrich

氟乙酸乙酯

98%

别名:

2-氟乙酸乙酯, 单氟乙酸乙酯, 氟乙酸乙酯

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About This Item

线性分子式:
FCH2COOC2H5
CAS号:
分子量:
106.10
Beilstein:
1743761
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

表单

liquid

折射率

n20/D 1.375 (lit.)

沸点

119.3 °C/753 mmHg (lit.)

溶解性

water: soluble

密度

1.098 g/mL at 25 °C (lit.)

官能团

ester
fluoro

SMILES字符串

CCOC(=O)CF

InChI

1S/C4H7FO2/c1-2-7-4(6)3-5/h2-3H2,1H3

InChI key

VCYZVXRKYPKDQB-UHFFFAOYSA-N

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一般描述

氟乙酸乙酯为酯类有机溶剂

应用

在 4-脱氧-4-氟毒蕈碱的合成中使用了氟乙酸乙酯 。将其用作合成(二乙氧基磷酰基)氟乙酸乙酯的起始试剂 。它被用于开发基于氨解的微胶囊化工艺

警示用语:

Danger

危险分类

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

87.8 °F - closed cup

闪点(°C)

31 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

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Reactivity of ethyl acetate and its derivatives toward ammonolysis: ramifications for ammonolysis-based microencapsulation process.
Chung Y, et al.
Polymers For Advanced Technologies, 20(10), 785-794 (2009)
A Convenient Synthesis of Ethyl(Diethoxyphosphoryl) fluoroacetate from Ethyl Fluoroacetate.
Elkik E and Imbeaux M.
Synthesis, 1989(11), 861-862 (1989)
P Bravo et al.
Journal of medicinal chemistry, 35(17), 3102-3110 (1992-08-21)
Four isomers of [(4-fluoro-5-methyl-tetrahydrofuran-2-yl)methyl]trimethylammonium iodide (4-deoxy-4-fluoro-muscarines) were prepared in enantiomerically and diastereomerically pure form from (S)-(-)-methyl 4-methylphenyl sulfoxide, ethyl fluoroacetate, and allyl bromide. Their absolute configurations were assigned by 1H NMR analyses. The four optically pure compounds were tested in
Youngwook Park et al.
The journal of physical chemistry letters, 9(15), 4282-4286 (2018-07-13)
Chemical reactions are extremely difficult to occur in ice at low temperature, where atoms and molecules are frozen in position with minimal thermal energy and entropy. Contrary to this general behavior, certain weak acids including fluoroacetic acids dissociate spontaneously and

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