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质量水平
方案
99%
表单
liquid
折射率
n20/D 1.494 (lit.)
沸点
126-128 °C (lit.)
密度
1.219 g/mL at 25 °C (lit.)
官能团
chloro
fluoro
SMILES字符串
Fc1cccc(Cl)c1
InChI
1S/C6H4ClF/c7-5-2-1-3-6(8)4-5/h1-4H
InChI key
VZHJIJZEOCBKRA-UHFFFAOYSA-N
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一般描述
Reaction of 1-chloro-3-fluorobenzene radical cation with NH3 has been investigated by FT-ICR spectrometry. It reacts with n-butyllithium to yield bicycloadducts via trapping of intermediate benzynes.
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
68.0 °F - closed cup
闪点(°C)
20 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Reactions of dihalobenzene radical cations with ammonia in the gas phase. Reactivity pattern for nucleophilic aromatic substitution.
Tholmann D and Gruetzmacher HF.
Journal of the American Chemical Society, 113(9), 3281-3287 (1991)
Antonio Ramírez et al.
Journal of the American Chemical Society, 126(45), 14700-14701 (2004-11-13)
The key elimination step for the formation of 3-chloro- and 3-fluorobenzyne from 2-chloro-6-fluorophenyllithium displays a pronounced solvent-dependent regioselectivity. 6Li and 13C NMR spectroscopic studies on 2-chloro-6-fluorophenyllithium reveal a single monomeric aryllithium, suggested by DFT computational studies to be a trisolvate.
Oriol Planas et al.
Science (New York, N.Y.), 367(6475), 313-317 (2020-01-18)
Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo oxidative addition, reductive elimination, and transmetallation in a manner
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