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Merck
CN

158402

Sigma-Aldrich

二环己烷并-18-冠醚-6

98%

别名:

2,3,11,12-双环己基-1,4,7,10,13,16-六氧环十八烷, 2,5,8,15,18,21-六氧杂三环[20.4.0.09.14]二十六烷, 二环己基并-18-冠醚-6, 全氢-二苯并-18-冠-6

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About This Item

经验公式(希尔记法):
C20H36O6
CAS号:
分子量:
372.50
Beilstein:
1130529
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

solid

SMILES字符串

C1CCC2OCCOCCOC3CCCCC3OCCOCCOC2C1

InChI

1S/C20H36O6/c1-2-6-18-17(5-1)23-13-9-21-11-15-25-19-7-3-4-8-20(19)26-16-12-22-10-14-24-18/h17-20H,1-16H2

InChI key

BBGKDYHZQOSNMU-UHFFFAOYSA-N

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相关类别

应用

阴离子活化剂,并作为络合剂溶解非极性溶剂中的碱金属离子。

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Oral - Eye Irrit. 2

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Giorgio Della Sala et al.
Organic & biomolecular chemistry, 11(5), 726-731 (2012-11-03)
The synthesis, complexation properties and catalytic activities under phase-transfer (PT) conditions of differently substituted cyclohexapeptoids are reported. Association constants, for small cationic alkali, and catalytic performances, in a model nucleophilic substitution, are comparable to those of representative crown ethers. Noteworthy
P Arhem et al.
Acta physiologica Scandinavica, 114(4), 593-600 (1982-04-01)
A potassium carrying ionophore dicyclohexano-18-crown-6 was found to affect the specific ionic currents in the node of Ranvier. Its presence caused an inactivation of the potassium permeability mechanism and a decrease of the sodium permeability. The rate of inactivation of
Aldrichimica Acta, 9, 3-3 (1976)
Aldrichimica Acta, 4, 1-1 (1971)
Svetlana V Smirnova et al.
Analytical and bioanalytical chemistry, 378(5), 1369-1375 (2004-01-30)
Amino acids Trp, Gly, Ala, Leu are extracted efficiently from aqueous solution at pH 1.5-4.0 (Lys and Arg at pH 1.5-5.5) into the room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF(6)) with dicyclohexano-18-crown-6 (CE). The most hydrophilic amino acids such as

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