148504
三苯基硅烷
97%
别名:
1,1′,1′′-三苯基硅烷, NSC 12565, 三苯基硅烷
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线性分子式:
(C6H5)3SiH
化学文摘社编号:
分子量:
260.41
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-333-0
Beilstein/REAXYS Number:
978182
MDL number:
产品名称
三苯基硅烷, 97%
InChI key
AKQNYQDSIDKVJZ-UHFFFAOYSA-N
InChI
1S/C18H16Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
SMILES string
c1ccc(cc1)[SiH](c2ccccc2)c3ccccc3
assay
97%
form
solid
reaction suitability
reagent type: reductant
bp
152 °C/2 mmHg (lit.)
mp
43-45 °C (lit.)
Quality Level
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Application
作为以下反应的反应物或试剂：
- 用于硅烷的催化氢氘交换反应
- 碳纳米管-金纳米复合物的氧化
- 用于钌配合物的水解
- 用于氢化硅烷化，以产生烯醇硅烷
- 用于合成溴硅烷
- 用于甲硅烷基烯烃的臭氧氧化，以合成α-O-甲硅烷基化偶姻衍生物
- 用于合成氢化甲硅烷基和双(甲硅烷基)双(咪唑啉基)镍配合物
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
168.8 °F - closed cup
flash_point_c
76 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Sylwia Członka et al.
Materials (Basel, Switzerland), 13(7) (2020-04-16)
In this work, rigid polyurethane (PUR) foams were prepared by incorporating 2 wt% of eucalyptus fibers. The eucalyptus fibers were surface-modified by maleic anhydride, alkali, and silane (triphenylsilanol) treatment. The impact of the modified eucalyptus fibers on the mechanical, thermal
Courtney M Olson et al.
The Journal of chemical physics, 147(12), 124302-124302 (2017-10-02)
Fourier transform infrared and two-dimensional IR (2D-IR) spectroscopies were applied to two different silanes in three different solvents. The selected solutes exhibit different degrees of vibrational solvatochromism for the Si-H vibration. Density functional theory calculations confirm that this difference in
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