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Merck
CN

138827

Sigma-Aldrich

1,3,5-三甲氧基苯

ReagentPlus®, ≥99%

别名:

间苯三酚三甲醚

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About This Item

线性分子式:
C6H3(OCH3)3
CAS号:
分子量:
168.19
Beilstein:
1307993
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

产品线

ReagentPlus®

方案

≥99%

表单

solid

沸点

255 °C (lit.)

mp

50-53 °C (lit.)

SMILES字符串

COc1cc(OC)cc(OC)c1

InChI

1S/C9H12O3/c1-10-7-4-8(11-2)6-9(5-7)12-3/h4-6H,1-3H3

InChI key

LKUDPHPHKOZXCD-UHFFFAOYSA-N

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一般描述

1,3,5-三甲氧基苯可有效地裂解各种醇和酸上的甲氧基苄基保护基。它是中国玫瑰品种中的主要芳香化合物

应用

1,3,5-三甲氧基苯用于研究1,2-苯并二亚苯基亚砜的光致脱氧反应。它被用作药物定量质子NMR光谱的二级标准品。

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Nicolas Kern et al.
The Journal of organic chemistry, 77(20), 9227-9235 (2012-09-26)
The p-methoxybenzyl protecting group (PMB) on various alcohols and an acid was efficiently and selectively cleaved by the action of a catalytic amount of silver(I) hexafluoroantimonate combined with 0.5 equiv of 1,3,5-trimethoxybenzene in dichloromethane at 40 °C.
Shuiqin Wu et al.
Plant physiology, 135(1), 95-102 (2004-05-04)
1,3,5-Trimethoxybenzene is a key component of the Chinese rose odor. This compound is synthesized in three successive methylation steps from phloroglucinol, the initial precursor. A novel, to our knowledge, phloroglucinol O-methyltransferase (POMT) characterized here methylates the first step to produce
Xichen Cai et al.
The journal of physical chemistry. A, 111(10), 1788-1791 (2007-02-14)
One-electron oxidation of alcohols such as methanol, ethanol, and 2-propanol by 1,3,5-trimethoxybenzene radical cation (TMB*+) in the excited state (TMB*+*) was observed during the two-color two-laser flash photolysis. TMB*+ was formed by the photoinduced bimolecular electron-transfer reaction from TMB to
Xichen Cai et al.
The journal of physical chemistry. A, 111(22), 4743-4747 (2007-05-08)
Bimolecular hole transfer quenching of the 1,3,5-trimethoxybenzene radical cation (TMB*+) in the excited state (TMB*+*) by hole quenchers (Q) such as biphenyl (Bp), naphthalene (Np), anisole (An), and benzene (Bz) with higher oxidation potentials than that of TMB was directly
O Chassany et al.
Alimentary pharmacology & therapeutics, 25(9), 1115-1123 (2007-04-19)
Abdominal pain is the predominant symptom in irritable bowel syndrome patients. Phloroglucinol and its methylated derivative are antispasmodic agents acting on smooth muscle. To evaluate the efficacy of phloroglucinol/trimethylphloroglucinol on pain intensity during an acute exacerbation of pain of irritable

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