127574
3,4-环氧-1-丁烯
98%
别名:
2-乙烯基环氧乙烷, 3,4-环氧-1-丁烯, 环氧丁烯
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关于此项目
经验公式（希尔记法）:
C4H6O
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
213-210-4
Beilstein/REAXYS Number:
103170
MDL number:
InChI key
GXBYFVGCMPJVJX-UHFFFAOYSA-N
InChI
1S/C4H6O/c1-2-4-3-5-4/h2,4H,1,3H2
SMILES string
C=CC1CO1
assay
98%
form
liquid
refractive index
n20/D 1.417 (lit.)
bp
65-66 °C (lit.)
density
0.87 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-58.0 °F - closed cup
flash_point_c
-50 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Stereoselective ring expansion of vinyl oxiranes: mechanistic insights and natural product total synthesis.
Matthew Brichacek et al.
Angewandte Chemie (International ed. in English), 49(9), 1648-1651 (2010-02-06)
Eduardo Cemeli et al.
Mutation research, 664(1-2), 69-76 (2009-05-12)
The toxicity of butadiene and styrene is exerted by their metabolites. Such metabolites have been extensively scrutinized at the in vitro level demonstrating evident genotoxic properties. In monitoring, a diverse range of outcomes has been produced. Additionally, epidemiological studies in
Thomas J L Mustard et al.
Journal of the American Chemical Society, 135(4), 1471-1475 (2013-01-01)
Density functional theory computations of the Cu-catalyzed ring expansion of vinyloxiranes is mediated by a traceless dual Cu(I)-catalyst mechanism. Overall, the reaction involves a monomeric Cu(I)-catalyst, but a single key step, the Cu migration, requires two Cu(I)-catalysts for the transformation.
M W Himmelstein et al.
Chemico-biological interactions, 135-136, 703-713 (2001-06-09)
(1-Chloroethenyl)oxirane (CEO) is a metabolite of beta-chloroprene (2-chloro-1,3-butadiene, CD). The purpose of this study was to evaluate the in vitro mutagenic and clastogenic (chromosome breaking) potential of CEO. For comparative purposes, the study also included an evaluation of the racemic
L Recio et al.
Chemico-biological interactions, 135-136, 325-341 (2001-06-09)
1,3-Butadiene (BD) is a multisite carcinogen and is mutagenic in multiple tissues of B6C3F1 mice. BD is bioactivated to at least three directly mutagenic metabolites: 1,2-epoxybutene (EB), 1,2-epoxy-3,4-butanediol (EBD), and 1,2,3,4-diepoxybutane (DEB). However, the contribution of these individual metabolites to
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