124141
4-溴苯乙烯
contains 0.05% 3,5-di-tert-butylcatechol as inhibitor, 97%
别名:
1-(4-溴苯基)乙烯, 1-溴-4-乙烯基苯, 1-溴-4-乙烯苯, 4-乙烯基-1-溴苯, 对溴苯乙烯
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关于此项目
线性分子式:
H2C=CHC6H4Br
化学文摘社编号:
分子量:
183.05
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
218-022-6
Beilstein/REAXYS Number:
1634204
MDL number:
产品名称
4-溴苯乙烯, contains 0.05% 3,5-di-tert-butylcatechol as inhibitor, 97%
InChI key
WGGLDBIZIQMEGH-UHFFFAOYSA-N
InChI
1S/C8H7Br/c1-2-7-3-5-8(9)6-4-7/h2-6H,1H2
SMILES string
Brc1ccc(C=C)cc1
assay
97%
form
liquid
contains
0.05% 3,5-di-tert-butylcatechol as inhibitor
refractive index
n20/D 1.594 (lit.)
bp
89 °C/16 mmHg (lit.)
density
1.4 g/mL at 25 °C (lit.)
storage temp.
−20°C
Quality Level
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Application
4-溴苯乙烯已用于以下研究：
- 苯乙烯乙烯基的化学和生化特性的结构活性相关性 (SAR) 研究。
- 合成具有4-代苯乙烯基取代基的倍半硅氧烷(SQ)。
- 调查光Br端自组装单层(SAMs) 在二氧化硅(111)上的光化学生长。
- 通过Heck反应合成聚(1,4-亚苯基亚乙烯基)。
- 通过烯烃交叉复分解合成硝基烯烃。
General description
4-溴苯乙烯是对卤代苯乙烯衍生物。只有当最低频率的扭转运动发生在大约80cm-1处时，4-溴苯乙烯的质子谱才显示出与平面基态结构一致的偶极耦合。在乙酸钠和Hermann催化剂存在的情况下，其可在N,N-二甲基乙酰胺中与2-溴-6-甲氧基萘进行Heck反应，得到二芳基乙烯。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Graham P Marsh et al.
Organic letters, 9(14), 2613-2616 (2007-06-07)
A synthesis of highly functionalized nitroalkenes is reported that utilizes a cross metathesis (CM) reaction between simple aliphatic nitro compounds and a range of substituted alkenes. This chemistry offers a simple and attractive route to nitroalkenes that would otherwise be
Synthesis and characterization of new hexahelicene derivatives.
Aloui F, et al.
Tetrahedron Letters, 48(11), 2017-2020 (2007)
Synthesis of monomers and polymers by the Heck reaction.
Heitz W, et al.
Makromol. Chem., 189(1), 119-127 (1988)
M Z Asuncion et al.
Journal of the American Chemical Society, 132(11), 3723-3736 (2010-03-02)
Polyphenylsilsesquioxane [PhSiO(1.5)](n) (PPS) and polyvinylsilsesquioxane [vinylSiO(1.5)](n) (PVS) are polymeric byproducts of the syntheses of the related T(8) octamers [PhSiO(1.5)](8) and [vinylSiO(1.5)](8). Here we demonstrate that random-structured PPS and PVS rearrange in the presence of catalytic amounts of Bu(4)N(+)F(-) in THF
Structural characterization of 4-bromostyrene self-assembled monolayers on Si (111).
Basu R, et al.
Langmuir, 23(4), 1905-1911 (2007)
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