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Merck
CN

119342

Sigma-Aldrich

(二甲基氨基甲基)二茂铁

≥95%

别名:

(二茂铁)二甲胺, N,N-二甲基二茂铁甲基胺, 二茂铁甲基胺

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About This Item

经验公式(希尔记法):
C13H17FeN
CAS号:
分子量:
243.13
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥95%

反应适用性

core: iron
reagent type: catalyst

折射率

n20/D 1.59 (lit.)

沸点

124-128 °C/2.5 mmHg (lit.)

密度

1.228 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2

InChI

1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;

InChI key

JJJSTEANRWLZBH-UHFFFAOYSA-N

一般描述

二甲基氨基甲基二茂铁(DMAMF)是一种二茂铁,由二甲基氨基甲基取代基连接其中一个配体而成。用作前体制备氧化铁膜。

应用

二甲基氨基甲基二茂铁用于:
  • 作为前体通过原子层沉积(ALD)制备氧化铁和镁掺杂氧化铁膜。
  • 作为胺配体用于合成五羰基(二甲基氨基甲基二茂铁)钨络合物。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Structural and magnetic studies on iron oxide and iron-magnesium oxide thin films deposited using ferrocene and (dimethylaminomethyl) ferrocene precursors
ECS Journal of Solid State Science and Technology, 2(3), N45-N45 (2012)
A N Shevel'kova et al.
Biokhimiia (Moscow, Russia), 58(6), 928-937 (1993-06-01)
The effects of dimethylaminomethylferrocene (DMAMF) on amylose and maltodextrins destruction by gluco-, alpha- and beta-amylases have been studied. The nature of DMAMF effects depends on the action mechanism of amylases and structure of their active sites. The effect observed is
Directly fused highly substituted naphthalenes via Pd-catalyzed dehydrogenative annulation of N, N-dimethylaminomethyl ferrocene using a redox process with a substrate
Zhang H, et al.
Organic Letters, 14(12), 3012-3015 (2012)
Yoshihiro Kase et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 20(8), 1143-1146 (2004-09-09)
We propose an electron transfer-mediated amperometric enzyme biosensor based on plasma-polymerized thin film of dimethylaminomethylferrocene (DMAMF) on a sputtered gold electrode. The DMAMF plasma-polymerized film is deposited directly onto the surface of the electrode under dry conditions. The resulting thin
S Takenaka et al.
Analytical biochemistry, 218(2), 436-443 (1994-05-01)
Electrochemically active DNA probes were prepared by linking a ferrocene unit with 5'-aminohexyl-terminated oligonucleotides. The DNA sequences of probes 5a, 5b, and 5c were 5'-T12-3', 5'-T20-3', and 5'-TGCAG TTCCG GTGGC TGATC-3', respectively. Probe 5a could form a complex selectively with

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