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Merck
CN

119342

Sigma-Aldrich

(二甲基氨基甲基)二茂铁

≥95%

别名:

(二茂铁)二甲胺, N,N-二甲基二茂铁甲基胺, 二茂铁甲基胺

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About This Item

经验公式(希尔记法):
C13H17FeN
CAS号:
分子量:
243.13
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥95%

反应适用性

core: iron
reagent type: catalyst

折射率

n20/D 1.59 (lit.)

沸点

124-128 °C/2.5 mmHg (lit.)

密度

1.228 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2

InChI

1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;

InChI key

JJJSTEANRWLZBH-UHFFFAOYSA-N

一般描述

二甲基氨基甲基二茂铁(DMAMF)是一种二茂铁,由二甲基氨基甲基取代基连接其中一个配体而成。用作前体制备氧化铁膜。

应用

二甲基氨基甲基二茂铁用于:
  • 作为前体通过原子层沉积(ALD)制备氧化铁和镁掺杂氧化铁膜。
  • 作为胺配体用于合成五羰基(二甲基氨基甲基二茂铁)钨络合物。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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S Takenaka et al.
Analytical biochemistry, 218(2), 436-443 (1994-05-01)
Electrochemically active DNA probes were prepared by linking a ferrocene unit with 5'-aminohexyl-terminated oligonucleotides. The DNA sequences of probes 5a, 5b, and 5c were 5'-T12-3', 5'-T20-3', and 5'-TGCAG TTCCG GTGGC TGATC-3', respectively. Probe 5a could form a complex selectively with
V N Goral et al.
Biochemistry and molecular biology international, 45(1), 61-71 (1998-06-23)
Reactivity of horseradish peroxidase compounds I and II (HRP-I and HRP-II) toward organometallicic substrates, viz water-soluble ferrocenes RFc (R = COOH and CH2NMe2), has been studied at 25 degrees C, pH 6.0 and ionic strength 0.1 M. The second-order rate
Guozhen Liu et al.
Analytica chimica acta, 909, 1-8 (2016-02-07)
A stable label-free amperometric immunosensor is presented based on gold nanoparticles and graphene oxide nanocomposites for detection of cardiac troponin-I in the early diagnosis of myocardial infarction. For designing of the sensing platform, firstly the nanocomposites based on GO and
[(Dimethylamino)methyl] ferrocene as an Amine Ligand: Study of the Bonding and X-Ray Crystal and Molecular Structure of the Pentacarbonyl{[(dimethylamino)methyl] ferrocene}tungsten Complex
Fischer A, et al.
Collection of Czechoslovak Chemical Communications, 67(2), 228-234 (2002)
Structural and magnetic studies on iron oxide and iron-magnesium oxide thin films deposited using ferrocene and (dimethylaminomethyl) ferrocene precursors
ECS Journal of Solid State Science and Technology, 2(3), N45-N45 (2012)

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