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Merck
CN

11268

四乙基碳酸氢铵

≥95.0% (T), solid

别名:

Tetraethylammonium hydrogen carbonate

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关于此项目

线性分子式:
(CH3CH2)4N(HCO3)
化学文摘社编号:
分子量:
191.27
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

四乙基碳酸氢铵, ≥95.0% (T)

SMILES string

OC([O-])=O.CC[N+](CC)(CC)CC

InChI

1S/C8H20N.CH2O3/c1-5-9(6-2,7-3)8-4;2-1(3)4/h5-8H2,1-4H3;(H2,2,3,4)/q+1;/p-1

InChI key

XUBMPLUQNSSFHO-UHFFFAOYSA-M

assay

≥95.0% (T)

form

solid

Quality Level

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Application

四乙基碳酸氢铵:
  • 用于由胺合成氨基甲酸酯。
  • 作为沉淀剂,通过共沉淀法合成 Cu/ZnO 催化剂。
  • 作为 [18] 放射性氟化中传统相转移系统的替代,用于防止微反应器堵塞。
  • 用于在恶唑烷-2,4-二酮的合成中,促进在 α-位上带有离去基团的二级甲酰胺的羧化。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetraethylammonium hydrogen carbonate in organic synthesis: Synthesis of oxazolidine-2, 4-diones.
Cesa S, et al.
Tetrahedron, 55(1), 193-200 (1999)
Ying Fu et al.
Journal of proteomics, 130, 108-119 (2015-09-19)
Powdery mildew (Pm), caused by Blumeria graminis f. sp. tritici (Bgt), is one of the most important crop diseases, causing severe economic losses to wheat production worldwide. However, there are few reports about the proteomic response to Bgt infection in
A convenient method for the synthesis of carbamate esters from amines and tetraethylammonium hydrogen carbonate.
Inesi A, et al.
The Journal of Organic Chemistry, 63(4), 1337-1338 (1998)
Jae-Ung Lee et al.
Physical chemistry chemical physics : PCCP, 22(9), 5057-5069 (2020-02-20)
Graph theory-based reaction pathway searches (ACE-Reaction program) and density functional theory calculations were performed to shed light on the mechanisms for the production of [an + H]+, xn+, yn+, zn+, and [yn + 2H]+ fragments formed in free radical-initiated peptide
Evaluation of tetraethylammonium bicarbonate as a phase-transfer agent in the formation of [18F] fluoroarenes.
Reed CD, et al.
Journal of Fluorine Chemistry, 143(4), 231-237 (2012)

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