109576
1,1′-二甲基二茂铁
95%, solid
别名:
双(甲基环戊二烯基)铁
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关于此项目
经验公式（希尔记法）:
C12H14Fe
化学文摘社编号:
分子量:
214.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-067-3
MDL number:
产品名称
1,1′-二甲基二茂铁, 95%
InChI key
GJFIEPAJMYPAGC-UHFFFAOYSA-N
InChI
1S/2C6H7.Fe/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;
SMILES string
[Fe].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2
assay
95%
form
solid
reaction suitability
core: iron, reagent type: catalyst
mp
37-40 °C (lit.)
Quality Level
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
226.4 °F - closed cup
flash_point_c
108.00 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
D J Claremont et al.
Diabetologia, 29(11), 817-821 (1986-11-01)
Miniature, amperometric glucose sensors were constructed using entrapped 1,1'-dimethylferrocene to mediate electron transfer between immobilised glucose oxidase and a carbon base electrode. Electrodes were calibrated in buffered glucose solutions and then implanted in the subcutaneous tissue of anaesthetised, non-diabetic pigs.
K B Male et al.
Applied biochemistry and biotechnology, 44(1), 91-100 (1994-01-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (Hp-beta-CyD), a cyclic and nonreducing oligosaccharide was used to enclose a hydrophobic guest molecule 1,1'-dimethylferrocene (DMF) to form a water-soluble yellow complex. At high concentrations (300 mM), Hp-beta-CyD enclosed up to 100 mM DMF. The yellow complex was
J H Luong et al.
Journal of molecular recognition : JMR, 8(1-2), 132-138 (1995-01-01)
Inclusion complexes of 1,1'-dimethylferrocene (DMFe) with alpha-, 2-hydroxypropyl-beta- or gamma-cyclodextrins were formed in aqueous systems. For the first time, the interacting DMFe-cyclodextrin systems have been characterized using cyclic voltammetry which enabled the estimation of the complexation order, the formation constant
M Wenzel et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 43(11-12), 963-966 (1988-11-01)
The relative stabilities of different ferricinium cations were studied in buffer or serum-containing solution and in vivo and compared with their cytostatic effects in cultures of Yoshida ascites tumor cells. Although the ferricinium cation itself was the most unstable cation
J H Luong et al.
Analytical biochemistry, 212(1), 269-276 (1993-07-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (hp-beta-CyD), a cyclic and nonreducing oligosaccharide, was used to enclose the hydrophobic guest molecules ferrocene (FeCp2) and 1,1'-dimethylferrocene (DMFeCp2) to form a water-soluble complex. At high concentrations (300 mM), hp-beta-CyD enclosed up to 100 mM FeCp2 or DMFeCp2.
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