推荐产品
质量水平
方案
99%
表单
solid
折射率
n20/D 1.479 (lit.)
沸点
210-211 °C (lit.)
密度
1.796 g/mL at 25 °C (lit.)
官能团
chloro
fluoro
SMILES字符串
Fc1c(F)c(F)c(c(F)c1F)S(Cl)(=O)=O
InChI
1S/C6ClF5O2S/c7-15(13,14)6-4(11)2(9)1(8)3(10)5(6)12
InChI key
UOJCTEGNHXRPKO-UHFFFAOYSA-N
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一般描述
Pentafluorobenzenesulfonyl chloride reacts with benzene and thiophene derivatives in the presence of a ruthenium (II) catalyst to form corresponding perfluorophenylated compounds.
应用
Pentafluorobenzenesulfonyl chloride was used as derivatizing reagent for simultaneous determination of fluoxetine and p-trifluoromethylphenol, an O-dealkylated metabolite of fluoxetine in human liver microsomes. Pentafluorobenzenesulfonyl chloride was used for electrophore labeling of small tyrosyl peptides for their analysis by gas chromatography with electron-capture detection.
生化/生理作用
Pentafluorobenzenesulfonyl chloride is derivatizing reagent for amphetamine in determination of amphetamine in human plasma samples using gas chromatography with electron-capture detectio.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
194.0 °F - closed cup
闪点(°C)
90 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
S J Asghar et al.
Journal of pharmacological and toxicological methods, 46(2), 111-115 (2002-12-17)
Acute administration of (+)-amphetamine has been used as a model for mania in humans since it mimics the physiological, biochemical, and cognitive effects seen in mania. A rapid and sensitive method for the determination of amphetamine in human plasma samples
Perfluorophenylation of aromatic and heteroaromatic compounds with pentafluorobenzenesulfonyl chloride catalyzed by a ruthenium (II) phosphine complex.
Kamigata N, et al.
Journal of Fluorine Chemistry, 87(1), 91-95 (1998)
Pentafluorobenzenesulfonyl chloride as a sensitive reagent for the rapid gas chromatographic analysis of tranylcypromine in tissues and body fluids.
T S Rao et al.
Biochemical pharmacology, 35(12), 1925-1928 (1986-06-15)
G B Baker et al.
Journal of chromatography, 381(2), 211-217 (1986-09-05)
A gas chromatographic procedure is described for the analysis of beta-phenylethylamine (PEA) in tissues and body fluids. The method involves the use of pentafluorobenzenesulfonyl chloride for extraction and derivatization of PEA. This is followed by separation and analysis of the
Pentafluorobenzenesulfonyl chloride: a new electrophoric derivatizing reagent with application to tyrosyl peptide determination by gas chromatography with electron capture detection.
A Sentissi et al.
Analytical chemistry, 56(13), 2512-2517 (1984-11-01)
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