931950
Sodium perchlorate
≥99.9% trace metals basis
别名:
Sodium Perchlorate, Hyperchloric acid sodium salt
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Assay:
≥99.9% trace metals basis
Grade:
anhydrous
Form:
powder
Solubility:
H2O: 209 g/dL at 15 °C
产品名称
Sodium perchlorate, ≥99.9% trace metals basis
SMILES string
[Na+].[Cl](=O)(=O)(=O)[O-]
InChI
1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
BAZAXWOYCMUHIX-UHFFFAOYSA-M
grade
anhydrous
assay
≥99.9% trace metals basis
form
powder
reaction suitability
core: sodium
impurities
≤1000 ppm (trace metals analysis)
pH
6.0-8.0 (25 °C, 5%, aq.sol.)
mp
482 °C
solubility
H2O: 209 g/dL at 15 °C
anion traces
chloride (Cl-): ≤30 ppm
sulfate (SO42-): ≤20 ppm
cation traces
Fe: ≤5 ppm
K: ≤500 ppm
Quality Level
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Application
The major application of anhydrous sodium perchlorate is as an electrolyte in sodium-ion batteries. It is popular because of its solubility in ethers and carbonates, its wide electrochemical stability window (e.g. from 0 to 5 V vs Na+/Na in propylene carbonate, triglyme, or diethylcarbonate)[1], and its compatibility with a wide range of materials. It has been used in batteries with hard-carbon anodes[2], mesoporous carbon anodes[3], sodium cobalt oxide cathodes (NaxCoO2)[4], sodium vanadium oxide cathodes (NaxVO2)[5], titanium dioxide cathodes[6], and emerging materials like high-entropy layered oxide cathodes[7].
General description
Anhydrous sodium perchlorate is a white crystalline solid. It is hygroscopic and absorbs water to form its monohydrate. Anhydrous sodium perchlorate is highly soluble in water, and soluble in a range of polar organic solvents such as methanol, ethanol, acetone, carbonates (including ethylene carbonate, dimethyl carbonate, propylene carbonate, and diethyl carbonate), and ethers (including dimethoxyethane, tetrahydrofuran, and triethylene glycol dimethyl ether). It is insoluble in benzene, chloroform, and toluene.
Packaging
10 g in glass bottle
25 g in glass bottle
25 g in glass bottle
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1 - STOT RE 2
target_organs
Thyroid
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 1
法规信息
易制爆化学品
危险化学品
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Chenglong Zhao et al.
Angewandte Chemie (International ed. in English), 59(1), 264-269 (2019-10-18)
Material innovation on high-performance Na-ion cathodes and the corresponding understanding of structural chemistry still remain a challenge. Herein, we report a new concept of high-entropy strategy to design layered oxide cathodes for Na-ion batteries. An example of layered O3-type NaNi0.12
Gianluca Longoni et al.
Nano letters, 17(2), 992-1000 (2016-12-28)
Rechargeable sodium-ion batteries are becoming a viable alternative to lithium-based technology in energy storage strategies, due to the wide abundance of sodium raw material. In the past decade, this has generated a boom of research interest in such systems. Notwithstanding
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries.
Komaba, S., et al.
Advances in Functional Materials, 21, 3859-3867 (2011)
Marie Guignard et al.
Nature materials, 12(1), 74-80 (2012-11-13)
Layered oxides are the subject of intense studies either for their properties as electrode materials for high-energy batteries or for their original physical properties due to the strong electronic correlations resulting from their unique structure. Here we present the detailed
R Berthelot et al.
Nature materials, 10(1), 74-80 (2010-12-15)
Sodium layered oxides NaxCoO2 form one of the most fascinating low-dimensional and strongly correlated systems; in particular P2–NaxCoO2 exhibits various single-phase domains with different Na+/vacancy patterns depending on the sodium concentration. Here we used sodium batteries to clearly depict the
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Discover the role of electrolytes in sodium-ion batteries, to enhance performance, safety, and sustainability in energy storage solutions.
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