- Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.
Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.
Chemical communications (Cambridge, England) (2012-10-16)
Daniel P Iwaniuk, Christian Wolf
PMID23064632
摘要
A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.