343641
( R )-(+)-香茅醛
technical grade
别名:
(+)-香茅醛, (3R)-3,7-二甲基-6-辛烯醛
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关于此项目
线性分子式:
(CH3)2C=CHCH2CH2CH(CH3)CH2CHO
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12352114
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-194-5
Beilstein/REAXYS Number:
1720791
MDL number:
Form:
liquid
产品名称
( R )-(+)-香茅醛, technical grade
InChI key
NEHNMFOYXAPHSD-SNVBAGLBSA-N
InChI
1S/C10H18O/c1-9(2)5-4-6-10(3)7-8-11/h5,8,10H,4,6-7H2,1-3H3/t10-/m1/s1
SMILES string
C[C@H](CC\C=C(\C)C)CC=O
grade
technical grade
form
liquid
refractive index
n20/D 1.448 (lit.)
bp
207 °C (lit.)
density
0.851 g/mL at 25 °C (lit.)
functional group
aldehyde
Quality Level
Application
(R)-(+)-香茅醛可用作反应剂合成各种化合物，包括L-薄荷醇、caparratriene和含氧族元素的硝酮衍生物。
General description
(R)-(+)-香茅醛是一种单萜醛。这种手性有机物可作为有机合成砌块制备各种手性化合物。也可用作不对称反应的手性催化剂或配体。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Xiangxian Ying et al.
Molecules (Basel, Switzerland), 24(6) (2019-03-21)
The members of the Old Yellow Enzyme (OYE) family are capable of catalyzing the asymmetric reduction of (E/Z)-citral to (R)-citronellal-a key intermediate in the synthesis of L-menthol. The applications of OYE-mediated biotransformation are usually hampered by its insufficient enantioselectivity and
Walter S Leal et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(46), 18704-18709 (2013-10-30)
The southern house mosquito, Culex quinquefasciatus, has one of the most acute and eclectic olfactory systems of all mosquito species hitherto studied. Here, we used Illumina sequencing to identify olfactory genes expressed predominantly in antenna, mosquito's main olfactory organ. Less
Gabriele Siedenburg et al.
Applied and environmental microbiology, 78(4), 1055-1062 (2011-12-14)
The biosynthesis of cyclic monoterpenes (C(10)) generally requires the cyclization of an activated linear precursor (geranyldiphosphate) by specific terpene cyclases. Cyclic triterpenes (C(30)), on the other hand, originate from the linear precursor squalene by the action of squalene-hopene cyclases (SHCs)
Alina Mariana Balu et al.
Organic & biomolecular chemistry, 8(12), 2845-2849 (2010-05-01)
The selective conversion of citronellal to menthols, with good diastereoselectivities to (-)-menthol for the case of (+)-citronellal as starting material, can effectively be carried out in a one-step reaction under microwave irradiation catalysed by supported nanoparticles on mesoporous materials. 2%
Daniel P Iwaniuk et al.
Chemical communications (Cambridge, England), 48(91), 11226-11228 (2012-10-16)
A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.
实验方案
-β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene
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