- Highly stereoselective synthesis of cis-β-enaminones mediated by diethyl azodicarboxylate.
Highly stereoselective synthesis of cis-β-enaminones mediated by diethyl azodicarboxylate.
Chemical communications (Cambridge, England) (2012-01-06)
Xiaoliang Xu, Ping Du, Dongping Cheng, Hong Wang, Xiaonian Li
PMID22218457
摘要
Promoted by diethyl azodicarboxylate, a novel and highly stereoselective synthesis of cis-β-enaminones via oxidative dehydrogenation and hydration of the substituted propargylamines was realized. The possible mechanism was also proposed.