推荐产品
产品线
Vetec™
表单
liquid
浓度
0.1 N in acetic acid
SMILES字符串
OCl(=O)(=O)=O
InChI
1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)
InChI key
VLTRZXGMWDSKGL-UHFFFAOYSA-N
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应用
Perchloric acid (in acetic acid) can be used as a detosylating agent for the deprotection of the tosyl functional groups in p-methyl benzene sulfonyl derivatives of primary, secondary aryl amines, and chiral aminoketones. It can also be used in the aromatic mercuration reaction.
法律信息
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
Perchloric Acid catalyzed aromatic mercuration in acetic acid solution. II. The Substitution Process
Kresge, A and Brennan, J
The Journal of Organic Chemistry, 32(3), 752-755 (1967)
Perchloric Acid-Acetic Acid: A Reagent System for Detosylation
Kudav, DP, et al.
Synthetic Communications, 17(10), 1185-1187 (1987)
John Greenwood et al.
ACS nano, 9(5), 5520-5535 (2015-04-22)
We shine light on the covalent modification of graphite and graphene substrates using diazonium chemistry under ambient conditions. We report on the nature of the chemical modification of these graphitic substrates, the relation between molecular structure and film morphology, and
Martin G Liebensteiner et al.
Science (New York, N.Y.), 340(6128), 85-87 (2013-04-06)
Perchlorate and chlorate anions [(per)chlorate] exist in the environment from natural and anthropogenic sources, where they can serve as electron acceptors for bacteria. We performed growth experiments combined with genomic and proteomic analyses of the hyperthermophile Archaeoglobus fulgidus that show
Dipanwita Das et al.
Journal of the American Chemical Society, 135(7), 2825-2834 (2013-02-12)
Selective two-electron plus two-proton (2e(-)/2H(+)) reduction of O(2) to hydrogen peroxide by ferrocene (Fc) or 1,1'-dimethylferrocene (Me(2)Fc) in the presence of perchloric acid is catalyzed efficiently by a mononuclear copper(II) complex, [Cu(II)(tepa)](2+) (1; tepa = tris[2-(2-pyridyl)ethyl]amine) in acetone. The E(1/2)
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