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Merck
CN

CRM06772

Supelco

氯溴隆

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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别名:
氯溴隆
经验公式(希尔记法):
C9H10BrClN2O2
CAS号:
分子量:
293.54
Beilstein:
2128736
MDL编号:
UNSPSC代码:
41116107
NACRES:
NA.24

等级

certified reference material
TraceCERT®

质量水平

产品线

TraceCERT®

保质期

limited shelf life, expiry date on the label

制造商/商品名称

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

储存温度

2-8°C

SMILES字符串

CON(C)C(=O)Nc1ccc(Br)c(Cl)c1

InChI

1S/C9H10BrClN2O2/c1-13(15-2)9(14)12-6-3-4-7(10)8(11)5-6/h3-5H,1-2H3,(H,12,14)

InChI key

NLYNUTMZTCLNOO-UHFFFAOYSA-N

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相关类别

一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Chlorbromouron is an obsolete systemic phenylurea herbicide used for pre- and post- emergence control of annual grasses (e.g. foxtail) and broad leafed weeds (e.g. chickweed) on a variety of crops. It inhibits photosynthesis by interfering with the electron transfer in photosystem II. As per the commission regulation no 1107/2009, repealing the council directive 91/414/EEC, chlorobromouron is not approved for use in the European Union. A default maximum residue limit (MRL) of 0.01 mg/kg is set for chlorbromuron as per regulation (EC) no. 396/2005.

应用

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Chlorobromouron CRM can also be used as below:

  • Method development for the quantification of 25 polar pesticides in fruit, vegetable, and water samples using high-performance liquid chromatography(HPLC)
  • Separation and determination of 12 substituted phenylurea herbicides by HPLC in the study to assess the leaching of the herbicides in two agricultural soil samples
  • Development of an HPLC method with diode array detection following dispersive liquid-liquid microextraction to determine 11 phenylurea herbicides in natural waters
  • Investigation of 1,6-hexanediol ethoxylate diacrylate (HEDA)-based polymeric monoliths as a sorbent for the extraction of phenylurea herbicides from water samples
  • Multi-residue analysis of 250 pesticides in surface water samples using liquid chromatography- quadrupole-Orbitrap high resolution tandem mass spectrometry

法律信息

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Exclamation markEnvironment

警示用语:

Warning

危险分类

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Abiotic and biotic processes governing the fate of phenylurea herbicides in soils: a review
Hussain S, et al.
Critical reviews in environmental science and technology, 45(18), 1947- 1998 (2015)
Simón Navarro et al.
Journal of agricultural and food chemistry, 60(21), 5279-5286 (2012-05-15)
In this study, the potential groundwater pollution of 12 substituted phenylurea herbicides (chlorbromuron, chlorotoluron, diuron, fenuron, fluometuron, isoproturon, linuron, metobromuron, metoxuron, monolinuron, Monuron, and neburon) was investigated under laboratory conditions. For this purpose, leaching studies were conducted using disturbed soil
Determination of polar pesticides in water, vegetables, and fruits by high performance liquid chromatography
Amelin V G, et al.
Moscow University Chemistry Bulletin, 67(6), 275- 282 (2012)
Dispersive liquid-liquid microextraction for the determination of herbicides of urea derivatives family in natural waters by HPLC
Amelin VG, et al.
Journal of Analytical Chemistry, 68(9), 822- 830 (2013)
Shu-Ling Lin et al.
Talanta, 147, 199-206 (2015-11-26)
In this study, recently developed 1,6-hexanediol ethoxylate diacrylate (HEDA)-based polymeric monoliths were utilized as sorbents for efficient extraction of phenylurea herbicides (PUHs) from water samples. The HEDA-based monolithic sorbents were prepared in a fused silica capillary (0.7mm i.d., 4.5-cm long)

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