等级
analytical standard
Agency
EPA 603,8240,8260
MISA (Canada) Group 18
蒸汽密度
1.94 (vs air)
蒸汽压
4.05 psi ( 20 °C)
描述
Separate Source
CofA
current certificate can be downloaded
自燃温度
428 °F
特点
standard type calibration
expl. lim.
31 %
包装
pkg of 1 × 100 mg (4S8501)
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.403 (lit.)
bp
53 °C (lit.)
mp
−87 °C (lit.)
溶解性
H2O: soluble
密度
0.839 g/mL at 25 °C (lit.)
应用
agriculture
environmental
格式
neat
储存温度
2-8°C
SMILES字符串
[H]C(=O)C=C
InChI
1S/C3H4O/c1-2-3-4/h2-3H,1H2
InChI key
HGINCPLSRVDWNT-UHFFFAOYSA-N
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一般描述
Acrolein is a carbonyl compound and a hazardous chemical, released into the environment through various manufacturing processes.
应用
Acrolein is used as an analytical reference standard for the quantification of the analyte in environmental matrices and biological samples using different chromatographic techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
-20.2 °F
闪点(°C)
-29 °C
个人防护装备
Faceshields, Gloves, Goggles
法规信息
危险化学品
Determination of acrolein in human urine by headspace gas chromatography and mass spectrometry
Sakura N, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 719(1-2), 209-212 (1998)
Simple Determination of Acrolein in Surface and Drinking Water by Headspace SPME GC?MS
Lim H-H and Shin S-H
Chromatographia, 75(15-16), 943-948 (2012)
Giancarlo Aldini et al.
Molecular nutrition & food research, 55(9), 1301-1319 (2011-08-02)
Acrolein (ACR) is a toxic and highly reactive α,β-unsaturated aldehyde widely distributed in the environment as a common pollutant and generated endogenously mainly by lipoxidation reactions. Its biological effects are due to its ability to react with the nucleophilic sites
Klaus Abraham et al.
Molecular nutrition & food research, 55(9), 1277-1290 (2011-09-08)
Acrolein is an α,β-unsaturated aldehyde formed by thermal treatment of animal and vegetable fats, carbohydrates and amino acids. In addition it is generated endogenously. As an electrophile, acrolein forms adducts with gluthathione and other cellular components and is therefore cytotoxic.
Mats Linder et al.
Physical chemistry chemical physics : PCCP, 15(14), 5108-5114 (2013-03-02)
This work discusses the dependence of transition state geometries on the choice of quantum chemical optimization method for the extensively studied Diels-Alder reaction. Rather significant differences are observed between post-Hartree-Fock methods and (hybrid) density functional theory, where the latter predicts
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