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Merck
CN

442869

三丁基氯化锡

analytical standard

别名:

TBTC, 氯化三丁基锡

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线性分子式:
[CH3(CH2)3]3SnCl
化学文摘社编号:
1461-22-9
分子量:
325.51
EC Number:
215-958-7
UNSPSC Code:
12352200
PubChem Substance ID:
24868030
Beilstein/REAXYS Number:
3535715
MDL number:
MFCD00000521

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产品名称

三丁基氯化锡, analytical standard

InChI key

GCTFWCDSFPMHHS-UHFFFAOYSA-M

InChI

1S/3C4H9.ClH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1

SMILES string

CCCC[Sn](Cl)(CCCC)CCCC

grade

analytical standard

vapor pressure

<0.01 mmHg ( 20 °C)

CofA

current certificate can be downloaded

packaging

ampule of 500 mg

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.492 (lit.)

bp

171-173 °C/25 mmHg (lit.)

density

1.2 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

storage temp.

2-30°C

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tributyltin chloride can be used as a precursor for the preparation of tributyltin (TBT) which may be used as a reference standard for the analysis of TBT in:
  • Seawater samples by gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS) with electron ionization (EI) and multiple reaction monitoring (MRM) modes of operation.
  • Sediment samples by static headspace (SHS) GC combined with MS operating in selected ion monitoring (SIM) mode.
  • Environmental water sample matrices by stir bar sorptive extraction (SBSE) with sodium tetrahydridoborate (NaBH4)-based in-situ derivatization combined with large-volume injection (LVI) GC-MS operating under the SIM mode of detection.
  • Natural waters by LVI using programmed temperature vaporization (PTV) injector-GC combined with inductively coupled plasma (ICP) MS.

General description

Tributyltin chloride is a salt derivative of tributyltin which is an organotin compound.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

226.4 °F - closed cup

flash_point_c

108 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
LRAD3379
LRAD6460
LRAC5557
LC18763V
LC26015V

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Development of a large volume injection method using a programmed temperature vaporization injector-gas chromatography hyphenated to ICP-MS for the simultaneous determination of mercury, tin and lead species at ultra-trace levels in natural waters.
Teran-Baamonde J, et al.
Journal of Chromatography A, 1547(3), 77-85 (2018)
Microbes a Tool for the Remediation of Organotin Pollution Determined by Static Headspace Gas Chromatography-Mass Spectrometry.
Finnegan C, et al.
Molecules (Basel), 23(3), 627-627 (2018)
Determination of tributyltin in environmental water matrices using stir bar sorptive extraction with in-situ derivatisation and large volume injection-gas chromatography-mass spectrometry.
Neng NR, et al.
Talanta, 126(3), 8-11 (2014)
Towards tributyltin quantification in natural water at the Environmental Quality Standard level required by the Water Framework Directive.
Alasonati E, et al.
Talanta, 160, 499-511 (2016)
Luca Amendola et al.
Analytica chimica acta, 975, 70-77 (2017-05-30)
Tributyltin (TBT) and pentachlorophenol (PCP) are listed as priority substances that warrant monitoring in the European Water Framework Directive (WFD 2000/60/CE), since TBT and PCP were identified as environmental endocrine disruptors and exhibit considerable toxicity toward both aquatic organisms and
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