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等级
analytical standard
蒸汽密度
4.62 (vs air)
蒸汽压
1.5 mmHg ( 20 °C)
3.7 mmHg ( 37.7 °C)
自燃温度
817 °F
expl. lim.
5.6 %
包装
ampule of 1000 mg
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.490 (lit.)
bp
176-178 °C (lit.)
密度
0.86 g/mL at 25 °C (lit.)
应用
environmental
格式
neat
SMILES字符串
CC(C)c1ccc(C)cc1
InChI
1S/C10H14/c1-8(2)10-6-4-9(3)5-7-10/h4-8H,1-3H3
InChI key
HFPZCAJZSCWRBC-UHFFFAOYSA-N
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应用
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3 - Repr. 2
WGK
WGK 2
闪点(°F)
125.6 °F
闪点(°C)
52 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chemistry, an Asian journal, 7(4), 788-801 (2012-02-07)
The reactions of two diaminotriazine ligands 2,4-diamino-6-(2-pyridyl)-1,3,5-triazine (2-pydaT) and 6-phenyl-2,4-diamino-1,3,5-triazine (PhdaT) with ruthenium-arene precursors led to a new family of ruthenium(II) compounds that were spectroscopically characterized. Four of the complexes were cationic, with the general formula [(η(6)-arene)Ru(κ(2)-N,N-2-pydaT)Cl]X (X=BF(4), TsO; arene=p-cymene:
Journal of the American Chemical Society, 134(18), 7588-7591 (2012-04-26)
Complex [(p-cymene)Ru(η(1)-O(2)CCF(3))(2)(OH(2))] mediated transformation of α-diazoacetamides ArCH(2)N(C(CH(3))(3))C(O)CHN(2) to result in carbene insertion into the primary C-H bond exclusively, with the γ-lactam products being isolated in up to 98% yield. This unexpected reaction is striking in view of the presence of
Organic letters, 14(8), 2146-2149 (2012-04-13)
The ruthenium(II) carboxylate complex [Ru(O(2)CMes)(2)(p-cymene)] enabled efficient direct arylations of unactivated C-H bonds with easily available, inexpensive phenols. Extraordinary chemoselectivity of the well-defined ruthenium catalyst set the stage for challenging C-H/C-O bond functionalizations to occur under solvent-free conditions as well
Inorganic chemistry, 51(2), 1057-1067 (2012-01-10)
The relative affinity of the cationic triangular metallaprism, [(pCH(3)C(6)H(4)Pr(i))(6)Ru(6)(tpt)(2)(dhbq)(3)](6+) ([1](6+)), for various amino acids, ascorbic acid, and glutathione (GSH) has been studied at 37 °C in aqueous solutions at pD 7, using NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS).
Chemistry (Weinheim an der Bergstrasse, Germany), 17(51), 14375-14379 (2011-11-25)
An easily accessible in situ catalyst composed of [{RuCl(2)(p-cymene)}(2)] and terpyridine has been developed for the selective transfer hydrogenation of aromatic nitro and azo compounds. The procedure is general and the selectivity of the catalyst has been demonstrated by applying
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