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Merck
CN

33001

Supelco

五氟溴苯 (PFB-Br)

analytical standard

别名:

2,3,4,5,6-五氟溴化苄, α-溴-2,3,4,5,6-五氟甲苯, (溴甲基)五氟苯

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About This Item

线性分子式:
C6F5CH2Br
CAS号:
分子量:
260.99
Beilstein:
647808
EC 号:
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:

等级

analytical standard
for GC derivatization

描述

Alkylation reagent

反应适用性

reagent type: derivatization reagent
reaction type: Alkylations

reagent type: derivatization reagent
reaction type: Esterifications

包装

ampule of 5 g

技术

gas chromatography (GC): suitable (ECD)

折射率

n20/D 1.471 (lit.)

沸点

174-175 °C (lit.)

mp

19-20 °C (lit.)

密度

1.728 g/mL at 25 °C (lit.)

SMILES字符串

Fc1c(F)c(F)c(CBr)c(F)c1F

InChI

1S/C7H2BrF5/c8-1-2-3(9)5(11)7(13)6(12)4(2)10/h1H2

InChI key

XDEPVFFKOVDUNO-UHFFFAOYSA-N

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一般描述

五氟苄基溴(PFB-Br)是一种衍生试剂。 过量的试剂可通过与氨基苯酚反应除去。它是一种烷基化试剂,适用于电子捕获检测器(ECD)检测。 同时也可作为催泪剂。

应用

它被用于通过负离子化学电离-气相色谱/质谱(NICI-GC / MS)分析D2 / E2-异前列腺素。在使用NICI-GC / MS测定脂肪酸的过程中,可以使用PFG-Br和二异丙基乙胺将脂肪酸转化为五氟苄基酯。

其他说明

五氟苄酯试剂。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

181.4 °F - closed cup

闪点(°C)

83 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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J D Morrow et al.
The Journal of biological chemistry, 269(6), 4317-4326 (1994-02-11)
We recently reported the discovery that a series of novel prostaglandin (PG)F2-like compounds (F2-isoprostanes) are produced in vivo independent of the cyclooxygenase as products of free radical-catalyzed lipid peroxidation. F2-isoprostanes are initially formed in situ from arachidonic acid esterified to
P O Edlumd et al.
Acta pharmacologica et toxicologica, 40(1), 145-152 (1977-01-01)
A highly sensitive gas-liquid chromatographic method with electron capture detection of clonidine in plasma is described. The alkaline samples (100-200mul) are extracted into cyclohexane-butanol (9:1), re-extracted into 0.1 N sulphuric acid, made alkaline and back-extracted into cyclohexane-butanol. The pentafluorobenzyl derivatives
J B Barham et al.
The Journal of nutrition, 130(8), 1925-1931 (2000-08-05)
Previous studies reveal that supplementation of human diets with gamma-linolenic acid (GLA) reduces the generation of lipid mediators of inflammation and attenuates clinical symptoms of chronic inflammatory disorders such as rheumatoid arthritis. However, we have shown that supplementation with this
Katja Dettmer-Wilde, Werner Engewald
Practical Gas Chromatography: A Comprehensive Reference, 616-616 (2014)
J A Coburn et al.
Journal - Association of Official Analytical Chemists, 59(1), 188-196 (1976-01-01)
A method for the quantitative determination of several N-methylcarbamates in natural waters and the applicability of the derivative to soil samples using a previously published extraction procedure are described. After extraction of the carbamates from the substrate, the carbamates are

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