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Merck
CN

T0514

Sigma-Aldrich

三甲胺N-氧化物 二水合物

98%

别名:

TMANO

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About This Item

线性分子式:
(CH3)3NO · 2H2O
CAS号:
分子量:
111.14
Beilstein:
3612927
EC 号:
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:

质量水平

方案

98%

表单

powder

反应适用性

reagent type: oxidant

mp

95-99 °C (lit.)

SMILES字符串

O.O.C[N+](C)(C)[O-]

InChI

1S/C3H9NO.2H2O/c1-4(2,3)5;;/h1-3H3;2*1H2

InChI key

PGFPZGKEDZGJQZ-UHFFFAOYSA-N

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应用

三甲胺N-氧化物二水合物可用作:
  • 许多化学反应中的脱羰剂
  • 有机硼烷的氧化剂
  • 标准品,用非抑制离子色谱法测定空气样品中的胺。

反应物用于:
  • C-H 键断裂
  • 氧化反应(氧化剂)

  • 用于无溶剂反应的脱碳剂

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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Thermal degradation of transition metal carbonyl complexes: Part IV: Thermogravimetric studies of various stoichiometric mixtures of trimethylamine N-oxide dihydrate and hexacarbonyl molybdenum
Chan HSO, et al.
Thermochimica Acta, 145, 179-187 (1989)
Oxidation of organoboranes with trimethylamine N-oxide dihydrate
Kabalka GW
Journal of Organometallic Chemistry, 125(2), 273-280 (1977)
Electrophilic attack on diphosphazane-bridged derivatives of diruthenium nonacarbonyl by halogens. Crystal structure of [Ru2 ({′A}-I) I (CO)3 {{′A}-(PriO)2 PN (Et)P (OPri)2}2]
John S, et al.
J. Chem. Soc., Dalton Trans., 10, 2761-2768 (1991)
Mark E Erupe et al.
Journal of chromatography. A, 1217(13), 2070-2073 (2010-02-26)
An ion chromatography method with non-suppressed conductivity detection was developed for the simultaneous determination of methylamines (methylamine, dimethylamine, trimethylamine) and trimethylamine-N-oxide in particulate matter air samples. The analytes were well separated by means of cation-exchange chromatography using a 3 mM
Hui Wei et al.
Frontiers in microbiology, 9, 3276-3276 (2019-01-29)
Yarrowia lipolytica, known to accumulate lipids intracellularly, lacks the cellulolytic enzymes needed to break down solid biomass directly. This study aimed to evaluate the potential metabolic burden of expressing core cellulolytic enzymes in an engineered high lipid-accumulating strain of Y.

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