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储存温度
2-8°C
质量水平
SMILES字符串
COC1OC2COC(OC2C3OC13)c4ccccc4
InChI
1S/C14H16O5/c1-15-14-12-11(18-12)10-9(17-14)7-16-13(19-10)8-5-3-2-4-6-8/h2-6,9-14H,7H2,1H3
InChI key
HQTCRHINASMQOA-UHFFFAOYSA-N
应用
Methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside has been used in a study to assess benzylidene acetal ring-opening of a 2-cyano-2-deoxypyranoside derivative. It has also been used in a study to describe new simple routes to the title epoxide using carbonate esters.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
María I Mangione et al.
Carbohydrate research, 338(21), 2177-2183 (2003-10-14)
The oxirane ring-opening of an anhydro sugar with diethylaluminum cyanide (Et(2)AlCN) is a direct approach for obtaining a cyano derivative. Methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside showed anomalous chemical behavior when treated with Et(2)AlCN. The reaction afforded the corresponding beta-cyanohydrin as the minor component
An alternative synthesis of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside using carbonate esters
Raaijmakers, H., et al.
Carbohydrate Research, 238, 185-192 (1993)
Reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside with ethanolamine and 1,4,7,10-tetraoxa-13-azacyclopentadecane
Toth, G., et al.
Carbohydrate Research, 168, 141-145 (1987)
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