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Merck
CN

C6696

Sigma-Aldrich

头孢菌素 来源于Cercospora hayii

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About This Item

经验公式(希尔记法):
C29H26O10
CAS号:
分子量:
534.51
MDL编号:
UNSPSC代码:
51102829
PubChem化学物质编号:
NACRES:
NA.85

表单

solid

质量水平

溶解性

chloroform: 9.80- 10.20 mg/mL, clear, red to red-brown

抗生素抗菌谱

Gram-positive bacteria

作用机制

cell membrane | interferes

储存温度

2-8°C

SMILES字符串

COC1=C(CC(C)O)c2c3c(CC(C)O)c(OC)c(O)c4C(=O)C=C5OCOc6cc(O)c(C1=O)c2c6c5c34

InChI

1S/C29H26O10/c1-10(30)5-12-18-19-13(6-11(2)31)29(37-4)27(35)21-15(33)8-17-23(25(19)21)22-16(38-9-39-17)7-14(32)20(24(18)22)26(34)28(12)36-3/h7-8,10-11,30-32,35H,5-6,9H2,1-4H3

InChI key

JWFLIMIGORGZMQ-UHFFFAOYSA-N

应用

尾孢菌素(C29H26O10)是一种从香蕉病原体培养物中分离出来的红色色素。它已被用于研究野油菜黄单胞菌百日菊致病变种(Bacterium Xanthomonas campestris pv. Zinniae )等物种的毒素生物降解

生化/生理作用

头孢菌素是一种聚酮化合物植物毒素,可以被光激活,并在激活状态下与氧气反应生成有毒氧物种,例如单线态氧(O2)和超氧化物(O2-)。活性氧的产生导致植物细胞膜中脂质的过氧化。
据报道,光诱导的聚酮化合物植物毒素在光催化下会产生单线态氧。

其他说明

保存于密闭容器内,置于干燥通风处。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Adam G Newman et al.
Chemical communications (Cambridge, England), 48(96), 11772-11774 (2012-10-31)
The polyketide synthase CTB1 is demonstrated to catalyze pyrone formation thereby expanding the known biosynthetic repertoire of thioesterase domains in iterative, non-reducing polyketide synthases.
Julia Knöckel et al.
The Biochemical journal, 443(2), 397-405 (2012-01-17)
The malaria parasite Plasmodium falciparum is able to synthesize de novo PLP (pyridoxal 5'-phosphate), the active form of vitamin B6. In the present study, we have shown that the de novo synthesized PLP is used by the parasite to detoxify
J D Williamson et al.
Trends in microbiology, 1(6), 239-245 (1993-09-01)
Antioxidant defense systems are a prominent element in plant responses to environmental stress. Activated oxygen species have themselves been implicated as both a part of the plant's defense against pathogen attack as well as the phytotoxic component of photosensitizing fungal
Maricela Martínez Jiménez et al.
Mycopathologia, 169(4), 309-314 (2009-11-27)
A red pigment produced by a Mexican isolate of Cercospora piaropi (waterhyacinth pathogen) has been isolated and identified as cercosporin. The kinetic of cercosporin production in culture media during dark/light regimes was evaluated. When C. piaropi was cultivated in continuous
Maricela Martínez Jiménez et al.
Mycopathologia, 167(4), 203-208 (2008-10-22)
An evaluation of the potential hazards associated with mutagenicity and acute toxicity of a mycoherbicide formulation based on the fungal pathogen Cercospora piaropi was performed. Neither the mycoherbicide nor any of its components were mutagenic to Salmonella typhimurium TA98 and

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