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Merck
CN
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文件

64255

Sigma-Aldrich

亚甲基二膦酸

for molecular studies & mass spectrometry

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别名:
MDP, 亚甲磷酸
线性分子式:
CH2[P(O)(OH)2]2
CAS号:
1984-15-2
分子量:
176.00
Beilstein:
1708494
MDL编号:
MFCD00002139
UNSPSC代码:
12352106
PubChem化学物质编号:
57651976
NACRES:
NA.52

质量水平

200

形式

powder

mp

197-199 °C (lit.)
201-205 °C

储存温度

2-8°C

SMILES字符串

OP(O)(=O)CP(O)(O)=O

InChI

1S/CH6O6P2/c2-8(3,4)1-9(5,6)7/h1H2,(H2,2,3,4)(H2,5,6,7)

InChI key

MBKDYNNUVRNNRF-UHFFFAOYSA-N

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一般描述

MDP（亚甲基二膦酸）是ATP的膦酸类似物。

应用

适用于
  • 天然二磷酸盐和三磷酸盐类似物的制备
  • 质谱研究作为分析标准
  • 与炎症相关的分子研究

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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H F Kung et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 19(9), 1027-1031 (1978-09-01)
Bidentate monophosphates--phosphonoacetate (PAA), 2-phosphonoproprionate (PPA), 2-methyl-2-phosphonoproprionate (MPPA), and carbamyl phosphate (CAP)--which are pyrophosphate analogs, were successfully labeled with Sn(II)-reduced [99mTc] pertechnetate in high yield (greater than 95%). Biodistribution studies show that these Tc-99m-labeled monophosphates do localize in bone. At 2
Phosphonic acid analogs of nucleoside phosphates. I. The synthesis of 5'-adenylyl methylenediphosphonate, a phosphonic acid analog of ATP
Myers TC et al
Journal of the American Chemical Society, 85, 3292-3295 (1963)
T G Rudd et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 18(9), 872-876 (1977-09-01)
The biologic and imaging characteristics of Tc-99m MDP and Tc-99m PPi were compared in animals and patients using freeze-dried bone-imaging kits. Biodistribution data in rabbits showed Tc-99m MDP had slightly higher bone uptake, significantly lower blood levels, and faster urinary
R. Engel
Chemical Reviews, 77, 349-349 (1977)
J.A. Stock
The Journal of Organic Chemistry, 44, 3997-3997 (1979)
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