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Merck
CN

54764

Sigma-Aldrich

新黄质

≥90% (HPLC)

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别名:
(3S, 3′S, 5 R, 5′R, 6 R, 6′S, 9′-顺式)-6,7-二脱氢-5′, 6′-环氧-5′, 6′-二氢-β, β-胡萝卜素-3,3′,5 (6 H)-三醇, 9′-顺式-新黄质
经验公式(希尔记法):
C40H56O4
CAS号:
分子量:
600.87
UNSPSC代码:
12352202
NACRES:
NA.32

质量水平

检测方案

≥90% (HPLC)

形式

solid

λ

in ethanol

紫外吸收

λ: 435-439 nm Amax

储存温度

−20°C

SMILES字符串

C/C(C([H])=[C@]=C1[C@](C)(O)C[C@@H](O)CC1(C)C)=C\C=C\C(C)=C\C=C\C=C(C)\C=C\C=C(/C=C/[C@@]2(O3)[C@@]3(C)C[C@@H](O)CC2(C)C)C

InChI

1S/C40H56O4/c1-29(17-13-19-31(3)21-22-35-36(5,6)25-33(41)27-38(35,9)43)15-11-12-16-30(2)18-14-20-32(4)23-24-40-37(7,8)26-34(42)28-39(40,10)44-40/h11-21,23-24,33-34,41-43H,25-28H2,1-10H3/b12-11+,17-13+,18-14+,24-23+,29-15+,30-16+,31-19+,32-20+/t22?,33-,34-,38+,39+,40-/m0/s1

InChI key

PGYAYSRVSAJXTE-CLONMANBSA-N

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应用

新黄素可用作参考标准品,以采用高效液相色谱法(HPLC)测定三角褐指藻提取物的酚含量和抗氧化活性。

生化/生理作用

新黄素是一种等位叶黄素,并且是菠菜和大麦叶等植物中主要的类胡萝卜素之一。橄榄油中也可以找到微量的这种色素。新黄素以两种异构体存在,即反式-新黄素和9′-顺式-新黄素。它也是脱落酸的前体。它可通过提供一般抗氧化活性产生光保护作用。新黄素具有凋亡和抗增殖作用。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Eiichi Kotake-Nara et al.
Cancer letters, 220(1), 75-84 (2005-03-02)
Neoxanthin and fucoxanthin, which have the characteristic structure of 5,6-monoepoxide and an allenic bond, were previously found to reduce the viability of human prostate cancer cells most intensively among 15 dietary carotenoids tested. In the present study, the induction of
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Molecules (Basel, Switzerland), 25(20) (2020-10-15)
Light is a paramount parameter driving photosynthesis. However, excessive irradiance leads to the formation of reactive oxygen species that cause cell damage and hamper the growth of photosynthetic organisms. Xanthophylls are key pigments involved in the photoprotective response of plants
Andrew A Pascal et al.
Nature, 436(7047), 134-137 (2005-07-08)
In order to maximize their use of light energy in photosynthesis, plants have molecules that act as light-harvesting antennae, which collect light quanta and deliver them to the reaction centres, where energy conversion into a chemical form takes place. The
Molecular approaches toward targeted cancer therapy with some food plant products: On the role of antioxidants and immune microenvironment
Khuda-Bukhsh A R, et al.
Cancer, 191-202 (2021)
F Bouvier et al.
European journal of biochemistry, 267(21), 6346-6352 (2000-10-13)
Neoxanthin, a precursor of the plant hormone abscisic acid, is an allenic xanthophyll recognized as the last product of carotenoid synthesis in green plants. A cDNA for neoxanthin synthase (NSY) was isolated from tomato using a molecular approach based on

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