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方案
≥95.0% (TLC)
浓度
16-22% Ca
包装形式
neat
储存温度
−20°C
SMILES字符串
O=C([H])COP([O-])([O-])=O.[Ca+2]
InChI
1S/C2H5O5P.Ca/c3-1-2-7-8(4,5)6;/h1H,2H2,(H2,4,5,6);/q;+2/p-2
InChI key
GDJKIYUDRLVKJE-UHFFFAOYSA-L
生化/生理作用
Oxidation of both the 2′- and 3′-positions of 2-deoxyribose can lead to the formation of the reactive electrophilic 2-phosphoglycolaldehyde which readily forms adducts with neighboring DNA bases, aldolase substrate
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Chemistry of α-Aminonitriles. Part 13. Formation of 2-Oxoethyl phosphates ('glycolaldehyde phosphates') from rac-Oxiranecarbonitrile and inorganic phosphate and on (formal) constitutional relationships between 2-Oxoethyl phosphates and oligo (hexo- and pentopyranosyl)nucleotide backbones.
Pitsch, S., et al.
Helvetica Chimica Acta, 77, 2251-2285 (1994)
M Awada et al.
Chemical research in toxicology, 14(9), 1247-1253 (2001-09-18)
Oxidation of deoxyribose in DNA results in the formation of a variety of electrophilic products that have the potential to react with nucleobases to form adducts. We now report that 2-phosphoglycolaldehyde, a model for the 3'-phosphoglycolaldehyde residue generated by 3'-oxidation
Chemistry of α-Aminonitriles. Aldomerisation of Glycolaldehyde Phosphate to rac-Hexose 2,4,6-Triphosphates and (in Presence of Formaldehyde) rac-Pentose 2,4-Diphosphates: rac-Allose 2,4,6-Triphosphate and rac-Ribose 2,4-Diphosphate Are the Main Reaction Products.
Mueller, D., et al.
Helvetica Chimica Acta, 73, 1410-1468 (1990)
Glycolaldehyde and glycolaldehyde phosphate as reaction components in enzymatic pentose formation.
J MARMUR et al.
Archives of biochemistry and biophysics, 31(1), 154-155 (1951-03-01)
Regulation of aspartate aminotransferase isozymes by D-erythrose 4-phosphate and glycolaldehyde phosphate, the naturally occurring homologues of D-glyceraldehyde 3-phosphate.
L Kopelovich et al.
The Journal of biological chemistry, 247(10), 3262-3268 (1972-05-25)
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