317861
异硫氰酸苯酯
99%, liquid, for protein sequencing
别名:
PITC
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关于此项目
线性分子式:
C6H5NCS
化学文摘社编号:
分子量:
135.19
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-138-1
MDL number:
Beilstein/REAXYS Number:
471392
产品名称
异硫氰酸苯酯, 99%, for protein sequencing
InChI key
QKFJKGMPGYROCL-UHFFFAOYSA-N
InChI
1S/C7H5NS/c9-6-8-7-4-2-1-3-5-7/h1-5H
SMILES string
S=C=Nc1ccccc1
type
for protein sequencing
assay
99%
form
liquid
refractive index
n20/D 1.6515 (lit.)
bp
218 °C (lit.)
221 °C
mp
−21 °C (lit.)
solubility
water: insoluble
density
1.132 g/mL at 20 °C (lit.)
functional group
isothiocyanate
storage temp.
2-8°C
Quality Level
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Application
用于伯胺和仲胺的衍生化试剂。用于通过 Edman 降解法进行多肽测序以及通过 HPLC 进行氨基酸分析。
自动序列分析时用于蛋白质 N-末端氨基酸的衍生化作用。二噻二氮杂富瓦烯的合成单体。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
190.4 °F - closed cup
flash_point_c
88 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Journal of the Chemical Society. Chemical Communications, 601-601 (1993)
F Lai et al.
BioTechniques, 14(4), 642-649 (1993-04-01)
Pre-column derivatizations of amino acids often present two major challenges: 1) automation, due to the multi-step manipulations for pH control, reagent addition, mixing and extraction, and 2) effect of matrices in the sample such as salts, buffers and surfactants. Both
Determination of phenylisothiocyanate derivatives of amphetamine and its analogues in biological fluids by HPLC-APCI-MS or DAD.
Bogusz MJ, et al.
Journal of Analytical Toxicology, 21(1), 59-69 (1997)
Amin Zolali et al.
Combinatorial chemistry & high throughput screening, 17(7), 610-613 (2014-03-19)
An efficient, one-pot and three-component synthesis of biologically important heterocyclic compounds is described from the reaction of primary amines and phenyl isothiocyanate in the presence of acryloyl chloride at room temperature without the need to use any catalyst.
One-pot dehydrations using phenyl isothiocyanate.
Majetich G, et al.
Tetrahedron Letters, 56(23), 3326-3329 (2015)
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