10609
9-Anthracenecarbonyl cyanide
BioReagent, suitable for fluorescence, ≥98.5% (GC)
别名:
α-Oxo-anthracene-9-acetonitrile, 9-Anthroyl nitrile
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关于此项目
经验公式（希尔记法）:
C16H9NO
化学文摘社编号:
分子量:
231.25
UNSPSC Code:
12352108
NACRES:
NA.32
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
8145431
产品名称
9-Anthracenecarbonyl cyanide, BioReagent, suitable for fluorescence, ≥98.5% (GC)
InChI key
FMKFDGUBVPIERQ-UHFFFAOYSA-N
InChI
1S/C16H9NO/c17-10-15(18)16-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)16/h1-9H
SMILES string
O=C(C#N)c1c2ccccc2cc3ccccc13
product line
BioReagent
assay
≥98.5% (GC)
form
solid
mp
142-143 °C (lit.)
solubility
DMF: soluble
acetonitrile: soluble
chloroform: soluble
fluorescence
λex 361 nm; λem 451 nm (after derivatization with ethanol)
λex 361 nm; λem 460 nm in methanol
suitability
suitable for fluorescence
storage temp.
−20°C
Quality Level
Other Notes
For derivatization of hydroxyl compounds for HPLC with fluorescence detection.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Application
9-Anthroyl nitrile is a fluorescent reagent useful in the derivatization of glucocorticoids to aid their detection and separation using RP-HPLC with fluorescence detection. It forms fluorescent esters by reacting with primary the hydroxyl group at the position 21 of the carbon chain on the glucocorticoid .
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
E Neufeld et al.
Journal of chromatography. B, Biomedical sciences and applications, 718(2), 273-277 (1998-12-05)
Corticosteroids containing a C21 primary hydroxyl group were derivatised with 9-anthroyl cyanide. The reagent was prepared as a solution in acetonitrile, containing 0.1% triethylamine, at a concentration of 2 mg/ml. Approximately 1 microg of corticosteroid was reacted with 100 microl
J. Goto et al.
Analytica Chimica Acta, 147, 397-397 (1983)
D A Owensby et al.
The Journal of biological chemistry, 264(30), 18180-18187 (1989-10-25)
Hepatic parenchymal cells contribute to the clearance of circulating tissue-type plasminogen activator (t-PA) in vivo. The hepatocyte extracellular matrix is interposed between the endothelial-lined sinusoids and the parenchymal cell surface and thus may influence t-PA clearance. To test this hypothesis
Thomas J Nelson
Analytical biochemistry, 419(1), 40-45 (2011-08-30)
A new ultrasensitive fluorescent derivatization procedure for chromatographic analysis of primary, secondary, and nonpolar tertiary alcohols is described. The procedure uses Bodipy FL in basic dichloromethane solution with Mukaiyama's reagent (2-chloro-1-methylpyridinium iodide) to form highly fluorescent ester derivatives that can
Y Saisho et al.
Analytical biochemistry, 252(1), 89-95 (1997-11-05)
A nonradioisotopic method has been developed for the determination of all-trans-farnesyl pyrophosphate (FPP), the common intermediate at the branch point of the biosynthesis of cholesterol and nonsterol end products, in dog and human plasma. FPP was cleaved to the parent
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