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经验公式(希尔记法):
H5IO6
化学文摘社编号:
分子量:
227.94
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
EC Number:
233-937-0
MDL number:
产品名称
高碘酸, ReagentPlus®, ≥99.0%
InChI key
TWLXDPFBEPBAQB-UHFFFAOYSA-N
InChI
1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
SMILES string
OI(O)(O)(O)(O)=O
product line
ReagentPlus®
assay
≥99.0%
form
powder or crystals
reaction suitability
reagent type: oxidant
technique(s)
toxicology assay: suitable
mp
122 °C (lit.)
solubility
water: 100 mg/mL, clear, colorless
Quality Level
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Application
周期酸可用于以下反应:
它还可用作:
- 醇到酮和醛的氧化。
- 氧化羟胺衍生物。
- 芳烃到醌的氧化。
它还可用作:
- 与醋酸铬(IV)一起作为化学计量氧化剂,用于叔 C−H 键到叔醇的氧化。
- 与氧化铬结合,将伯醇氧化为羧酸;烷基苯氧化为苯甲酸;环苯醚氧化为相应的内酯。
- 使用 FeCl3 作为催化剂,将硫化物选择性氧化为亚砜。
General description
周期酸是碘的氧化酸,通常用作强氧化剂。这种无机酸可溶于大多数溶剂,包括水和醚。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral
target_organs
Thyroid
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
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