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Merck
CN

P57506

Sigma-Aldrich

吡啶

ReagentPlus®, ≥99%

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About This Item

经验公式(希尔记法):
C5H5N
CAS号:
分子量:
79.10
Beilstein:
103233
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥99%
沸点:
115 °C (lit.)
蒸汽压:
10 mmHg ( 13.2 °C)
20 mmHg ( 25 °C)

蒸汽密度

2.72 (vs air)

质量水平

蒸汽压

10 mmHg ( 13.2 °C)
20 mmHg ( 25 °C)

产品线

ReagentPlus®

方案

≥99%

表单

liquid

自燃温度

899 °F

expl. lim.

12.4 %

杂质

≤0.1% water (Karl Fischer)

折射率

n20/D 1.509 (lit.)

pH值(酸碱度)

8.5 (25 °C, 15.82 g/L)

沸点

115 °C (lit.)

mp

−42 °C (lit.)

密度

0.978 g/mL at 25 °C (lit.)

SMILES字符串

C1=CN=CC=C1

InChI

1S/C5H5N/c1-2-4-6-5-3-1/h1-5H

InChI key

JUJWROOIHBZHMG-UHFFFAOYSA-N

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一般描述

吡啶(Pyr)是一种含氮的六元杂环化合物,在有机合成中常用作溶剂。它也广泛用作碱、催化剂和合成中间体。

应用

吡啶可作为溶剂用于:    
  • 以三氯乙腈作为活化剂合成糖磷脂和磷酸二酯或磷酸单酯。      
  • Knoevenagel 缩合反应。      
  • TEMPO 介导的 3-乙烯基吡啶自由基聚合。

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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象形图

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警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

68.0 °F - closed cup

闪点(°C)

20 °C - closed cup

法规信息

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分析证书(COA)

Lot/Batch Number

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访问文档库

Total syntheses of complanadines A and B.
Le Zhao et al.
Angewandte Chemie (International ed. in English), 52(6), 1722-1725 (2013-01-03)
Nathalie Ségaud et al.
Inorganic chemistry, 52(2), 691-700 (2013-01-11)
We report the synthesis, characterization, and solution chemistry of a series of new Fe(II) complexes based on the tetradentate ligand N-methyl-N,N'-bis(2-pyridyl-methyl)-1,2-diaminoethane or the pentadentate ones N,N',N'-tris(2-pyridyl-methyl)-1,2-diaminoethane and N,N',N'-tris(2-pyridyl-methyl)-1,3-diaminopropane, modified by propynyl or methoxyphenyltriazolyl groups on the amino functions. Six of
Bobby Happ et al.
Chemical Society reviews, 41(6), 2222-2255 (2011-11-15)
Pyridine-based ligands, such as 2,2'-bipyridine and 1,10-phenanthroline, have gained much interest in the fields of supramolecular chemistry as well as materials science. The appealing optoelectronic properties of their complexes with heavy d(6) transition metal ions, such as Ru(ii), Os(II), Re(I)
Ye Wei et al.
Journal of the American Chemical Society, 135(10), 3756-3759 (2013-02-27)
We describe here a [3+3]-type condensation reaction of O-acetyl ketoximes and α,β-unsaturated aldehydes that is synergistically catalyzed by a copper(I) salt and a secondary ammonium salt (or amine). This redox-neutral reaction allows modular synthesis of a variety of substituted pyridines
Wen Zhou et al.
Inorganic chemistry, 52(5), 2271-2273 (2013-02-20)
The reaction of 2,2'-bipyridine (bpy) with monomeric chromium(II) precursors was used to prepare the S = 1 complexes Cr(tBu-acac)2(bpy) (1) and (η(5)-Cp)(η(1)-Cp)Cr(bpy) (3), as well as the S = 2 compound Cr[N(SiMe3)2]2(bpy) (4). The crystallographically determined bond lengths indicate that

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