蒸汽密度
2.72 (vs air)
质量水平
蒸汽压
10 mmHg ( 13.2 °C)
20 mmHg ( 25 °C)
产品线
ReagentPlus®
检测方案
≥99%
形式
liquid
自燃温度
899 °F
expl. lim.
12.4 %
杂质
≤0.1% water (Karl Fischer)
折射率
n20/D 1.509 (lit.)
pH值(酸碱度)
8.5 (25 °C, 15.82 g/L)
bp
115 °C (lit.)
mp
−42 °C (lit.)
密度
0.978 g/mL at 25 °C (lit.)
SMILES字符串
C1=CN=CC=C1
InChI
1S/C5H5N/c1-2-4-6-5-3-1/h1-5H
InChI key
JUJWROOIHBZHMG-UHFFFAOYSA-N
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一般描述
吡啶(Pyr)是一种含氮的六元杂环化合物,在有机合成中常用作溶剂。它也广泛用作碱、催化剂和合成中间体。
应用
吡啶可作为溶剂用于:
- 以三氯乙腈作为活化剂合成糖磷脂和磷酸二酯或磷酸单酯。
- Knoevenagel 缩合反应。
- TEMPO 介导的 3-乙烯基吡啶自由基聚合。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
WGK
WGK 2
闪点(°F)
68.0 °F
闪点(°C)
20 °C
法规信息
危险化学品
Total syntheses of complanadines A and B.
Angewandte Chemie (International ed. in English), 52(6), 1722-1725 (2013-01-03)
Inorganic chemistry, 52(2), 691-700 (2013-01-11)
We report the synthesis, characterization, and solution chemistry of a series of new Fe(II) complexes based on the tetradentate ligand N-methyl-N,N'-bis(2-pyridyl-methyl)-1,2-diaminoethane or the pentadentate ones N,N',N'-tris(2-pyridyl-methyl)-1,2-diaminoethane and N,N',N'-tris(2-pyridyl-methyl)-1,3-diaminopropane, modified by propynyl or methoxyphenyltriazolyl groups on the amino functions. Six of
Chemical Society reviews, 41(6), 2222-2255 (2011-11-15)
Pyridine-based ligands, such as 2,2'-bipyridine and 1,10-phenanthroline, have gained much interest in the fields of supramolecular chemistry as well as materials science. The appealing optoelectronic properties of their complexes with heavy d(6) transition metal ions, such as Ru(ii), Os(II), Re(I)
Inorganic chemistry, 52(5), 2271-2273 (2013-02-20)
The reaction of 2,2'-bipyridine (bpy) with monomeric chromium(II) precursors was used to prepare the S = 1 complexes Cr(tBu-acac)2(bpy) (1) and (η(5)-Cp)(η(1)-Cp)Cr(bpy) (3), as well as the S = 2 compound Cr[N(SiMe3)2]2(bpy) (4). The crystallographically determined bond lengths indicate that
Journal of medicinal chemistry, 56(22), 9342-9350 (2013-11-01)
In this study, we developed an assignment-free approach for rapid identification of ligand-binding sites in target proteins by using NMR. With a sophisticated cell-free stable isotope-labeling procedure that introduces (15)N- or (13)C-labels to specific atoms of target proteins, this approach
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