质量水平
产品线
ReagentPlus®
检测方案
≥99.0%
形式
powder or crystals
pH值（酸碱度）
5.3-8.7 (25 °C, 97.2 g/L)
mp
173 °C (lit.)
SMILES字符串
[K]SC#N
InChI
1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
InChI key
ZNNZYHKDIALBAK-UHFFFAOYSA-M
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一般描述
Potassium thiocyanate (KSCN) is a potassium salt of thiocyanate anion. Its crystalline structure has been analyzed based on polarized infrared spectral data. The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been evaluated. It facilitates the ring opening of aziridines with high regioselectivity.
应用
Potassium thiocyanate may be used in the synthesis of the following:
- α-Amino nitriles from tertiary amines.
- Polysubstituted 2-aminothiazoles from vinyl azides.
- Benzisothiazol-3(2H)-one derivatives from o-bromobenzamides.
- Diaryl thioethers from aryl halides.
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1
补充剂危害
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Regioselective ring-opening of aziridines with potassium thiocyanate in the presence of β-cyclodextrin in water.
Reddy MS, et al.
Tetrahedron Letters, 46(38), 6437-6439 (2005)
Synthesis of diaryl thioethers from aryl halides and potassium thiocyanate.
Hajipour AR, et al.
Applied Organometallic Chemistry, 28(12), 879-879 (2014)
Potassium Thiocyanate as Source of Cyanide for the Oxidative α-Cyanation of Tertiary Amines.
Wagner A and Ofial AR.
The Journal of Organic Chemistry, 80(5), 2848-2854 (2015)
Iron (II)-Promoted Synthesis of 2-Aminothiazoles via C=N Bond Formation from Vinyl Azides and Potassium Thiocyanate.
Zhang G, et al.
Advanced Synthesis & Catalysis, 357(5), 1065-1069 (2015)
Polarized infrared spectrum of potassium thiocyanate.
Jones LH.
J. Chem. Phys. , 28(6), 1234-1236 (1958)
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