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Merck
CN

746371

Sigma-Aldrich

碘化钠

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99.5%

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线性分子式:
NaI
CAS号:
分子量:
149.89
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21

等级

ACS reagent
anhydrous

质量水平

蒸汽密度

>1 (vs air)

产品线

Redi-Dri

检测方案

≥99.5%

形式

powder

质量

free-flowing

杂质

≤0.002% N compounds
≤0.01% insolubles

pH值(酸碱度)

6.0-9.0 (25 °C, 5%)

mp

661 °C (lit.)

痕量阴离子

Cl- and Br-: ≤0.01%
iodate (IO3-): ≤3 ppm
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.005%

痕量阳离子

Ba: ≤0.002%
Ca: ≤0.002%
Fe: ≤5 ppm
K: ≤0.01%
Mg: ≤0.001%
heavy metals (as Pb): ≤5 ppm

SMILES字符串

[Na+].[I-]

InChI

1S/HI.Na/h1H;/q;+1/p-1

InChI key

FVAUCKIRQBBSSJ-UHFFFAOYSA-M

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一般描述

碘化钠是一种无机钠盐,通常在有机合成中用作碘离子的来源。通过亲核位移反应将烷基卤化物和磺酸盐转化为烷基碘化物和芳基碘化物。此外,NaI 还与氧化剂结合使用,用于有机硼烷、酚类和芳香族化合物的碘化。

应用

碘化钠可用于以下方面:      
  • NaI-AlCl3 在酮肟到苯胺的 Beckmann 重排中用作脱水剂。      
  • 以硅胶负载的氯化铈用作催化剂,以通过邻苯二胺与酮的反应合成 2,3-二氢-1H-1,5-苯二氮卓类药物。      
  • NaI-二氯二甲基硅烷催化体系用于将二芳基甲醇还原为相应的二芳基甲烷。

特点和优势

  • 提高效率——免除需要松散硬化粉末的时间和精力     
  • 更加安全——无需使用工具大力敲碎团块
  • 更加环保——不会粘在包装上,减少了浪费     
  • 更加经济——制备和溶剂化速度更快,提高效率并节约成本      
  • 质量保证——经过专业检测的出色品质,无抗结剂添加     
  • 灵活的用量选择——有从研究到放大级别的用量规格可供选择。

法律信息

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

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