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Merck
CN

71840

过硼酸钠 四水合物

purum p.a., 96% (RT)

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关于此项目

线性分子式:
NaBO3 · 4H2O
化学文摘社编号:
分子量:
153.86
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
239-172-9
MDL number:
Assay:
96% (RT)
Form:
powder or crystals
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InChI key

IBDSNZLUHYKHQP-UHFFFAOYSA-N

InChI

1S/BO3.Na.4H2O/c2-1-3-4-1;;;;;/h;;4*1H2/q-1;+1;;;;

SMILES string

O.O.O.O.[Na+].[O-]B1OO1

grade

purum p.a.

assay

96% (RT)

form

powder or crystals

concentration

≥10% (active oxygen)

pH

10-10.4 (25 °C, 10 g/L)

mp

60 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤500 mg/kg, sulfate (SO42-): ≤6000 mg/kg

cation traces

Ca: ≤200 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

Quality Level

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General description

过硼酸钠四水合物是一种水合钠盐。它参与苯胺和硫化物的多种氧化反应。

Application

过硼酸钠四水合物可用于以下研究:
  • 碘代芳烃转化为(二乙酰氧基碘代)芳烃。
  • 氧化 Π-缺乏的吖嗪,得到 N-氧化物。
  • 氧化含硫杂环化合物,得到 SS-二氧化物。
  • 微波辅助氧化水合各种芳香族和脂肪族腈。

signalword

Danger

target_organs

Respiratory system

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Repr. 1B - STOT SE 3

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

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Microwave-promoted transformation of nitriles to amides with aqueous sodium perborate.
Sharifi A, et al.
Synthetic Communications, 31(3), 431-434 (2001)
Further functional group oxidations using sodium perborate.
McKillop A and Kemp D.
Tetrahedron, 45(11), 3299-3306 (1989)
Divya S Sharma et al.
The Journal of clinical pediatric dentistry, 35(3), 289-294 (2011-06-18)
External root resorption is the complication of intra-coronal bleaching done with 30% H2O2 alone or mixed with sodium perborate but not with sodium perborate mixed with water. The study was done to comparatively evaluate the H2O2 leakage from three H2O2
Milton Carlos Kuga et al.
Dental traumatology : official publication of International Association for Dental Traumatology, 28(3), 238-242 (2011-11-22)
To compare the fracture resistance of bovine teeth after intracoronal bleaching with sodium percarbonate (SPC) or sodium perborate (SP) mixed with water or 20% hydrogen peroxide (HP). Fifty extracted bovine teeth were divided into four experimental groups (G1-G4) and one
Eduardo Buozi Moffa et al.
Journal of dentistry, 39 Suppl 3, e65-e71 (2011-11-03)
This randomised clinical study evaluated the effect of chemical disinfection with sodium perborate or chlorhexidine on the colour stability of a hard chairside reline resin during six months. Hard chairside reline resin (Tokuyama Rebase Fast II) was used to reline

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