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Merck
CN

71608

Sigma-Aldrich

六硝基钴酸钠(III)

puriss. p.a., for the determination of K, ACS reagent

别名:

亚硝酸钴钠, 六硝酸钴钠

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About This Item

线性分子式:
Na3Co(NO2)6
CAS号:
分子量:
403.94
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
表单:
powder

等级

ACS reagent
puriss. p.a.

质量水平

表单

powder

质量

for the determination of K

mp

220 °C (dec.) (lit.)

痕量阴离子

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤500 mg/kg

痕量阳离子

Ca: ≤50 mg/kg
Cd: ≤5 mg/kg
Cr: ≤50 mg/kg
Cu: ≤5 mg/kg
Fe: ≤20 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Ni: ≤20 mg/kg
Pb: ≤100 mg/kg
Zn: ≤10 mg/kg

适用性

in accordance for determination of potassium

SMILES字符串

[Na+].[Na+].[Na+].[O-][N+](=O)[Co-3]([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O

InChI

1S/Co.6NO2.3Na/c;6*2-1-3;;;/q-3;;;;;;;3*+1

InChI key

IMBXIBFCGMYSME-UHFFFAOYSA-N

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应用

Sodium hexanitrocobaltate(III) (Na3Co(NO2)6) may be employed as a nitrosation reagent for various amino group containing organic compounds (aliphatic and aromatic).

警示用语:

Danger

危险分类

Carc. 2 - Eye Irrit. 2 - Ox. Sol. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The thermal dissociation of sodium hexanitrocobaltate (III).
Wendlandt W and Southern T.
Journal of Thermal Analysis and Calorimetry, 2(1), 87-89 (1970)
D B Green et al.
Stain technology, 65(1), 15-24 (1990-01-01)
The effect was examined of the chemical decomposition of the potassium stain sodium hexanitrocobaltate (III) (SHC), on its ability to produce stain granules of consistent size that could be used to estimate the K+ contents of stomatal guard cells. Stomata
Bogdan Stefane et al.
The Journal of organic chemistry, 62(21), 7165-7169 (2001-10-24)
Na(3)Co(NO(2))(6) has been investigated as a new reagent for the nitrosation of various substrates containing an amino functionality. Reactions took place in an aqueous solution of the reagent. The pH of the reaction mixture remained in the range 4.3-5. Thus
[Hygienic standard basis for potassium hexanitrocobaltate in the water of reservoirs].
A A Korolev
Gigiena i sanitariia, (10)(10), 72-73 (1980-10-01)
G Krishnamoorthy et al.
Biochemistry, 41(51), 15277-15287 (2002-12-18)
Information on the structure and dynamics of condensed forms of DNA is important in understanding both natural situations such as DNA packaging and artificial systems such as gene delivery complexes. We have established the fluorescence of bisintercalator 1,1'-(4,4,8,8-tetramethyl-4,8-diazaundecamethylene)bis[4-[[3-methylbenz-1,3-oxazol-2-yl]methylidine]-1,4-dihydroquinolinium] tetraiodide (YOYO-1)

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