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Merck
CN

676918

Sigma-Aldrich

二硫化碳

ACS reagent, ≥99.9%

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About This Item

经验公式(希尔记法):
CS2
CAS号:
分子量:
76.14
Beilstein:
1098293
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21
等级:
ACS reagent
方案:
≥99.9%
沸点:
46 °C (lit.)
蒸汽压:
5.83 psi

等级

ACS reagent

质量水平

蒸汽密度

2.67 (vs air)

蒸汽压

5.83 psi

方案

≥99.9%

表单

liquid

自燃温度

212 °F

expl. lim.

50 %

杂质

H2S, passes test (lim. ~1.5 ppm)
SO2, passes test (lim. ~2.5 ppm)
≤0.05% water

蒸发残留物

≤0.002%

颜色

APHA: ≤10

折射率

n20/D 1.627 (lit.)

沸点

46 °C (lit.)

mp

−112-−111 °C (lit.)

密度

1.266 g/mL at 25 °C (lit.)

SMILES字符串

S=C=S

InChI

1S/CS2/c2-1-3

InChI key

QGJOPFRUJISHPQ-UHFFFAOYSA-N

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一般描述

Carbon disulfide is a widely used solvent in the production of rayon fibers, carbon tetrachloride, pesticides, vulcanizers, cellophane, adhesives, and other chemicals. It is also used as a starting material in the synthesis of various sulfur-containing derivatives.

应用

Carbon disulfide can be used as a solvent:
  • To synthesize hydroxynaphthyl ketones via Friedel-Crafts acylation and demethylation.
  • In the regioselective bromination of binaphthols.

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说明
价格

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1

靶器官

Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

-22.0 °F - closed cup

闪点(°C)

-30 °C - closed cup

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Margherita Maiuri et al.
Physical chemistry chemical physics : PCCP, 14(18), 6312-6319 (2012-02-15)
In carotenoids internal conversion between the allowed (S(2)) and forbidden (S(1)) excited states occurs on a sub-picosecond timescale; the involvement of an intermediate excited state(s) (S(x)) mediating the process is controversial. Here we use high time resolution (sub-20 fs) broadband
[11C]carbon disulfide: a versatile reagent for PET radiolabelling.
Philip W Miller et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(2), 433-436 (2011-12-14)
Marjan J Smeulders et al.
Nature, 478(7369), 412-416 (2011-10-21)
Extremophilic organisms require specialized enzymes for their exotic metabolisms. Acid-loving thermophilic Archaea that live in the mudpots of volcanic solfataras obtain their energy from reduced sulphur compounds such as hydrogen sulphide (H(2)S) and carbon disulphide (CS(2)). The oxidation of these
A critical review of the literature on carbon disulfide toxicity.
R O Beauchamp et al.
Critical reviews in toxicology, 11(3), 169-278 (1983-01-01)
R Guillemin et al.
Nature communications, 6, 6166-6166 (2015-01-22)
Electronic core levels in molecules are highly localized around one atomic site. However, in single-photon ionization of symmetric molecules, the question of core-hole localization versus delocalization over two equivalent atoms has long been debated as the answer lies at the

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