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About This Item
线性分子式:
LiClO4
CAS号:
分子量:
106.39
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥98.0% (calc. based on dry substance, T)
表单:
powder
溶解性:
alcohol: soluble(lit.)
water: soluble(lit.)
water: soluble(lit.)
推荐产品
等级
purum p.a.
质量水平
方案
≥98.0% (calc. based on dry substance, T)
表单
powder
反应适用性
reagent type: oxidant
杂质
≤3% water
pH值（酸碱度）
6.0-9.5 (25 °C, 106.4 g/L)
mp
236 °C (lit.)
溶解性
alcohol: soluble(lit.)
water: soluble(lit.)
痕量阴离子
chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤200 mg/kg
痕量阳离子
Ca: ≤100 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤500 mg/kg
Na: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg
SMILES字符串
[Li+].[O-]Cl(=O)(=O)=O
InChI
1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
MHCFAGZWMAWTNR-UHFFFAOYSA-M
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一般描述
Lithium perchlorate (LiClO4) is a colorless lithium salt. Upon crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO4.3H2O). It can be synthesized by reacting lithium chloride with perchloric acid.
应用
Lithium perchlorate (LiClO4) may be used as a catalyst in the synthesis of bis(indolyl)methanes and in the Baylis-Hillman coupling reaction of α,β-unsaturated carbonyl compounds with aldehydes.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
易制爆化学品
危险化学品
Lithium perchlorate-accelerated Baylis-Hillman reactions.
Kawamura M and Kobayashi S.
Tetrahedron Letters, 40(8), 1539-1542 (1999)
Lithium perchlorate catalyzed reactions of indoles: An expeditious synthesis of bis (indolyl) methanes.
Yadav JS, et al.
Synthesis, 2001(5), 0783-0787 (2001)
Witold Darlewski et al.
Journal of hazardous materials, 175(1-3), 460-467 (2009-11-17)
A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
Francisco Palacios et al.
The Journal of organic chemistry, 67(7), 2131-2135 (2002-04-02)
Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium
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