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Merck
CN

62580

高氯酸锂

purum p.a., ≥98.0% (calc. based on dry substance, T), powder

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关于此项目

线性分子式:
LiClO4
化学文摘社编号:
分子量:
106.39
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-237-2
MDL number:
Assay:
≥98.0% (calc. based on dry substance, T)
Form:
powder
Solubility:
alcohol: soluble(lit.)
water: soluble(lit.)
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产品名称

高氯酸锂, purum p.a., ≥98.0% (calc. based on dry substance, T), powder

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

grade

purum p.a.

assay

≥98.0% (calc. based on dry substance, T)

form

powder

reaction suitability

reagent type: oxidant

impurities

≤3% water

pH

6.0-9.5 (25 °C, 106.4 g/L)

mp

236 °C (lit.)

solubility

alcohol: soluble(lit.)
water: soluble(lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤200 mg/kg

cation traces

Ca: ≤100 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤500 mg/kg
Na: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

Quality Level

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Application

Lithium perchlorate (LiClO4) may be used as a catalyst in the synthesis of bis(indolyl)methanes and in the Baylis-Hillman coupling reaction of α,β-unsaturated carbonyl compounds with aldehydes.

General description

Lithium perchlorate (LiClO4) is a colorless lithium salt. Upon crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO4.3H2O). It can be synthesized by reacting lithium chloride with perchloric acid.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

存储类别

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

易制爆化学品
危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lithium perchlorate-accelerated Baylis-Hillman reactions.
Kawamura M and Kobayashi S.
Tetrahedron Letters, 40(8), 1539-1542 (1999)
Lithium perchlorate catalyzed reactions of indoles: An expeditious synthesis of bis (indolyl) methanes.
Yadav JS, et al.
Synthesis, 2001(5), 0783-0787 (2001)
Natalia Varaksa et al.
Proceedings of the National Academy of Sciences of the United States of America, 99(8), 5012-5017 (2002-04-18)
The adsorption of the trigonal connector, 1,3,5-tris[10-(3-ethylthiopropyl)dimethylsilyl-1,10-dicarba-closo-decaboran-1-yl]benzene (1), from acetonitrile/0.1 M LiClO(4) on the surface of mercury at potentials ranging from +0.3 to -1.4 V (vs. aqueous Ag/AgCl/1 M LiCl) was examined by voltammetry, Langmuir isotherms at controlled potentials, and
L H Sim et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 287-292 (2010-05-07)
The interaction behaviours between components of polyacrylate (PAc)/poly(ethylene oxide) (PEO) and lithium perchlorate (LiClO(4)) were investigated in detail by Attenuated Total Reflectance (ATR)-Fourier Transformed Infrared (FTIR) spectroscopy. Solution cast films of the PAc/PEO and PAc/PEO/LiClO(4) were examined. No obvious shifting
Paula A Brooksby et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 64(2), 372-382 (2005-12-31)
Attenuated total reflection infrared spectroscopy was used to examine the concentration dependent solvation of LiClO4 and NaClO4 electrolytes in propylene carbonate (PC). Factor analysis and curve fitting techniques were performed on the measured spectra and the results compared with ab

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