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About This Item
线性分子式:
H2SO4 · (SO3)x
CAS号:
分子量:
98.08
Beilstein:
2037554
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:
NACRES:
NA.21
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一般描述
Fuming sulfuric acid is an inorganic acid, that can be produced by the addition of sulfur trioxide to concentrated sulfuric acid. It is commonly used as a sulfonating reagent in sulfonation reactions. When fuming sulfuric acid is employed as reaction medium, bromination takes place only in the pyridine nucleus of isomeric methylpyridines and 2,6-dimethylpyridine. It can also oxidize fullerene C60 to form fullerene polymers.
应用
Fuming sulfuric acid may be used as a sulfonating agent for the synthesis of:
- sulfonated poly(1,4-phenylene sulfide)
- water-soluble polyphosphazene polyelectrolyte
- sulfated graphene
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Inhalation - Skin Corr. 1A - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Daley RF and Daley SJ.
Organic Chemistry, Part 3 of 3, 801-801 null
Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions.
Liu F, et al.
Journal of Materials Chemistry, 22(12), 5495-5502 (2012)
Bromination of methylpyridines in fuming sulfuric acid.
Van der Does L and Hertog HJD.
Rec. Trav. Chim., 84(7), 951-964 (1965)
Products of reaction of fullerene C60 with fuming sulfuric acid studied by IR and ESR spectroscopy.
Garkusha OG, et al.
Russian Chemical Bulletin, 51(4), 628-631 (2002)
Proton conducting composite membranes comprising sulfonated Poly(1,4-phenylene sulfide) and zeolite for fuel cell.
Choi JM, et al.
Ionics, 16(5), 403-408 (2010)
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