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Merck
CN

399124

Sigma-Aldrich

高锰酸钾

ACS reagent, ≥99.0%, low in mercury

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About This Item

经验公式(希尔记法):
KMnO4
CAS号:
分子量:
158.03
EC 号:
MDL编号:
UNSPSC代码:
12352312
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥99.0%
等级:
ACS reagent
表单:
solid
溶解性:
water: soluble 63.8 g/L at 20 °C(lit.)
acetone: soluble(lit.)
methanol: soluble(lit.)

等级

ACS reagent

质量水平

方案

≥99.0%

表单

solid

反应适用性

reagent type: oxidant

杂质

≤0.005% N compounds
≤0.2% insolubles

pH值(酸碱度)

7.2-9.7 (20 °C, 20 g/L)

溶解性

water: soluble 63.8 g/L at 20 °C(lit.)
acetone: soluble(lit.)
methanol: soluble(lit.)

痕量阴离子

chloride, chlorate (as Cl-): ≤0.005%
sulfate (SO42-): ≤0.02%

痕量阳离子

Hg: ≤0.05 ppm

SMILES字符串

[K+].[O-][Mn](=O)(=O)=O

InChI

1S/K.Mn.4O/q+1;;;;;-1

InChI key

VZJVWSHVAAUDKD-UHFFFAOYSA-N

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一般描述

Potassium permanganate (PP, KMnO4) is a dark violet colored crystalline solid. It is a strong oxidizing agent used in the oxidation of a wide range of organic compounds. PP is commonly used as a disinfectant to treat external infections in aquaculture. Corncobs pretreated with alkaline potassium permanganate solution showed high carbohydrate recovery due to the increased enzymatic hydrolysis of lignocellulose. The acidic potassium permanganate chemiluminescence detection has been employed for the detection of cannabinoids.

应用

Potassium permanganate was used in the preparation of layered MnO2 which may be employed as cathodic material in lithium secondary batteries.
It may be used as an oxidant in:
  • The reduction of polycyclic aromatic hydrocarbons found in coal tar pitches (CTPs).
  • Oxidation of decabromodiphenyl ether in sulfuric acid medium.
  • Oxidative cleavage of oximes to the corresponding carbonyl compounds potassium permanganate supported on kieselguhr.
  • Oxidation of progestagens.
适用于非均相氧化。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2 - Repr. 2 - Skin Corr. 1 - STOT RE 2 Inhalation

靶器官

Brain

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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访问文档库

Preparation of layered MnO2 via thermal decomposition of KMnO4 and its electrochemical characterizations.
Kim, S.H. et al.
Chemistry of Materials, 11(3), 557-563 (1999)
Reducing polycyclic aromatic hydrocarbons content in coal tar pitch by potassium permanganate oxidation and solvent extraction.
Wang W, et al.
Journal of Environmental Chemical Engineering, 3(3), 1513-1521 (2015)
Potassium Permanganate

Lee DG, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Screening of cannabinoids in industrial-grade hemp using two-dimensional liquid chromatography coupled with acidic potassium permanganate chemiluminescence detection.
Pandohee J, et al.
Journal of Separation Science, 38(12), 2024-2032 (2015)
Degradation of progestagens by oxidation with potassium permanganate in wastewater effluents.
Fayad PB, et al.
Chemistry Central Journal, 7, 84-84 (2013)

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