推荐产品
等级
ACS reagent
质量水平
方案
≥99.5%
表单
crystals
反应适用性
reagent type: oxidant
杂质
≤0.005% NH4OH ppt.
≤0.005% insolubles
pH值（酸碱度）
3.5 (20 °C, 100 g/L)
mp
91 °C (lit.)
痕量阴离子
chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.01%
痕量阳离子
Al: ≤0.002%
Ca: ≤0.003%
SMILES字符串
O.O.[Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O
InChI
1S/2Cr.2Na.2H2O.7O/h;;;;2*1H2;;;;;;;/q;;2*+1;;;;;;;;2*-1
InChI key
JYDRNIYTFCBIFC-UHFFFAOYSA-N
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一般描述
Sodium dichromate dehydrate (SDD), a hexavalent chromium compound is commonly used as an oxidizing agent. Chromium (VI) compounds are genotoxic and group 1 IARC (International Agency for Research on Cancer) carcinogen. SDD is one of the common contaminants found in drinking water. Its toxic effects and carcinogenicity has been studied.
应用
Sodium dichromate dehydrate may be used in preparing Jones reagent which is employed for oxidation reactions. It may be used in the oxidation of arylalkanes.
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation
储存分类代码
5.1B - Oxidizing hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
易制爆化学品
Shaken not stirred; oxidation of alcohols with sodium dichromate.
Lou JD, et al.
Tetrahedron Letters, 47(3), 311-313 (2006)
Chromium Oxidations in Organic Chemistry
Cainelli G and Cardillo G.
Chromium Oxidations in Organic Chemistry, 29-32G-29-32G (2012)
A chronic oral reference dose for hexavalent chromium-induced intestinal cancer.
Thompson CM, et al.
Journal of Applied Toxicology, 34(5), 525-536 (2014)
Lack of genotoxic effects in hematopoietic and gastrointestinal cells of mice receiving chromium (VI) with the drinking water.
De Flora S, et al.
Mutation Research, Reviews in Mutation Research, 659(1), 60-67 (2008)
Synthesis of novel types of polyester glycodendrimers as potential inhibitors of urinary tract infections.
Jean-d'Amour KT, et al.
New. J. Chem., 39(5), 4115-4127 (2015)
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