360589
四氢呋喃
≥99.0%, ACS reagent, contains 250 ppm BHT as inhibitor, suitable for HPLC
别名:
THF, 丁烯氧化物, 四亚甲基氧化物, 氧杂环戊烷
About This Item
143 mmHg ( 20 °C)
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产品名称
四氢呋喃, contains 250 ppm BHT as inhibitor, ACS reagent, ≥99.0%
等级
ACS reagent
质量水平
蒸汽密度
2.5 (vs air)
蒸汽压
114 mmHg ( 15 °C)
143 mmHg ( 20 °C)
方案
≥99.0%
表单
liquid
自燃温度
610 °F
包含
250 ppm BHT as inhibitor
expl. lim.
1.8-11.8 %
技术
HPLC: suitable
杂质
≤0.015% peroxide (as H2O2)
≤0.05% water
蒸发残留物
≤0.03%
颜色
APHA: ≤20
折射率
n20/D 1.407 (lit.)
pH值（酸碱度）
~7
沸点
65-67 °C (lit.)
mp
−108 °C (lit.)
溶解性
water: soluble
密度
0.889 g/mL at 25 °C (lit.)
SMILES字符串
C1CCOC1
InChI
1S/C4H8O/c1-2-4-5-3-1/h1-4H2
InChI key
WYURNTSHIVDZCO-UHFFFAOYSA-N
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一般描述
应用
- 有机合成
b) 有机金属化合物
c) Reformatsky
D) 锂化
e) 氢化物还原
f) 金属催化偶联(Heck, Stile, Suzuki)
g) 路易斯介导反应
- 结晶
- 聚合如对乙酰氧基苯乙烯的RAFT（可逆加成断裂链转移）聚合。
- 涂料
- 作为O-供体配体，形成配位络合物
- 作为高效液相色谱的流动相溶剂
特点和优势
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-6.2 °F - closed cup
闪点(°C)
-21.2 °C - closed cup
法规信息
Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.
How do I get lot-specific information or a Certificate of Analysis?
The lot specific COA document can be found by entering the lot number above under the "Documents" section.
Who do I contact about larger solvent volume needs?
Email us at labessentials@sial.com or visit Sigma-Aldrich Fine Chemicals for development and manufacturing-scale inquiries: safcglobal@sial.com
How do I know what packaging options are available for a solvent?
The Solvent Center gives you the ability to review all the specifications associated with our solvent packaging. This includes physical dimensions, closure types, dispensing methods, UN/DOT Rating as well as solvent compatibility. Visit the Solvent Center.
Who do I contact if I need a solvent blend, which you do not carry?
Email us at labessentials@sial.com. For a complete listing of all our Solvent blends, Visit the Solvent Center
The dispensing of solvents provides some challenges due to the number of container options available. What dispensing options are available for each container?
The Sigma-Aldrich Solvent Center provides numerous dispensing options for each container type. For a complete listing of all our dispensing options, Visit the Solvent Center.
Which solvent grade should I be using for my application?
Sigma-Aldrich Solvent Applications Table gives a guideline to common applications and the appropriate solvent grades. Visit: Solvents
What are the options for drying solvents?
Sigma-Aldrich offers a full range of high-purity solvents with extremely low water levels specifically manufactured for moisture sensitive Organic and Biotech applications. Sigma-Aldrich also carries various drying agents such as molecular sieves, which are typically compatible with organic solvents.
What apparatus do you recommend for HPLC solvent filtration?
The Sigma-Aldrich Vacuum Filtration Assembly gives you all the components you need including: funnel top, fritted glass funnel support, filtration flask, aluminum clamp, and silicone stopper. The Acrodisc Syringe Filters offer high quality filtration for analytical samples, certified for HPLC to ensure low extractable and available in a broad range of membranes to meet sample compatibility requirements.
Can you recommend a Solvent Extractor for organics from aqueous solution?
Solvent extractors are often used for the quantitative extraction of organics from aqueous solutions and separations in immunoassays. The MIXXOR system has been applied successfully in many laboratory solvent extraction operations and is ideal for the rapid screening of alternative solvents for specific extraction problems.
Why do peroxides form in certain solvents and how do I test for it?
A significant number of laboratory solvents can undergo autoxidation under normal storage conditions to form unstable and potentially dangerous peroxide by-products. Molecular structure is the primary factor relating to a material’s potential for hazardous peroxide formation. It is important to understand the stability of materials in use and if unclear, consult Sigma-Aldrich Technical Support, techserv@sial.com.
What are some of the preservatives used in the most common ethers and chlorinated solvents and why are they added?
Certain solvents will degrade over time requiring special handling and storage considerations. In addition, the products of certain degradation processes pose a potential safety risk if present at sufficiently high levels. For these types of materials, small amounts of stabilizing chemicals are added to slow down or stop material degradation.
How do I find price and availability?
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What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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