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等级
ACS reagent
质量水平
蒸汽密度
2.1 (vs air)
蒸汽压
2.7 mmHg ( 20 °C)
方案
≥95%
表单
liquid
自燃温度
784 °F
expl. lim.
7.3 %, 33 °F
杂质
≤0.05% water
颜色
APHA: ≤10
折射率
n20/D 1.382 (lit.)
pH值（酸碱度）
6.4 (20 °C, 0.01 g/L)
沸点
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
适用性
clear for appearance
SMILES字符串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
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一般描述
硝基甲烷是一种脂肪族硝基化合物，通常用作化学加工和分析的溶剂。
应用
硝基甲烷可作为溶剂用于：
- FeCl3-催化的吲哚与醇傅-克烷基化反应。
- 钴催化的醛肟脱水生成腈反应。
- 醇生成羰基化合物的化学选择性氧化反应。
- 金催化的芳基取代炔烃的氢芳基化反应。
警示用语：
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 2
闪点(°F)
95.0 °F - closed cup
闪点(°C)
35 °C - closed cup
法规信息
易制爆化学品
危险化学品
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Atanu Bhattacharya et al.
The Journal of chemical physics, 136(2), 024321-024321 (2012-01-21)
Decomposition of electronically excited nitro-containing molecules with different X-NO(2) (X = C, N, O) moieties has been intensively investigated over the past decades; however, their decomposition behavior has not previously been compared and contrasted. Comparison of their unimolecular decomposition behavior
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Xin Yang et al.
Environmental science & technology, 46(23), 12832-12838 (2012-11-17)
Nitrogenous disinfection byproducts (N-DBPs) such as haloacetonitriles (HANs) and halonitromethanes (HNMs) are formed during water chlorination. Preozonation is sometimes applied to control trihalomethane (THM) formation, but this may risk promoting the formation of HNMs and HANs. The role of ozone
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