等级
ACS reagent
质量水平
蒸汽密度
2.1 (vs air)
蒸汽压
2.7 mmHg ( 20 °C)
检测方案
≥95%
形式
liquid
自燃温度
784 °F
expl. lim.
7.3 %, 33 °F
杂质
≤0.05% water
颜色
APHA: ≤10
折射率
n20/D 1.382 (lit.)
pH值（酸碱度）
6.4 (20 °C, 0.01 g/L)
bp
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
适用性
clear for appearance
SMILES字符串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
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一般描述
硝基甲烷是一种脂肪族硝基化合物，通常用作化学加工和分析的溶剂。
应用
硝基甲烷可作为溶剂用于：
- FeCl3-催化的吲哚与醇傅-克烷基化反应。
- 钴催化的醛肟脱水生成腈反应。
- 醇生成羰基化合物的化学选择性氧化反应。
- 金催化的芳基取代炔烃的氢芳基化反应。
警示用语：
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
易制爆化学品
危险化学品
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Eagleson M.
Concise Encyclopedia Chemistry, 696-696 (1994)
Huachang Hong et al.
The Science of the total environment, 444, 196-204 (2012-12-29)
The formations of THMs, HAAs, and HNMs from chlorination and chloramination of water from Jinlan Reservoir were investigated in this study. Results showed that monochloramine rather than chlorine generally resulted in lower concentration of DBPs, and the DBPs formation varied
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